Stoichiometric valence versus structural valence:: conclusions drawn from a study of the influence of polyhedron distortion on bond valence sums

被引：19
作者：
Liebau, F
Wang, XQ
机构：
[1] Univ Kiel, Inst Geowissensch, D-24098 Kiel, Germany
[2] Univ Houston, Dept Chem, Houston, TX 77204 USA
来源：
ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 2005年 / 220卷 / 07期
关键词：
valence; stoichiometric valence; structural valence; polyhedron distortions; bond valence sums;
D O I：
10.1524/zkri.220.7.589.67103
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
From studies of the influence of polyhedron distortions on bond valence sums (BVS), it is concluded that larger deviations of the BVS values from corresponding values of their classical valence are due to the fact that so far no distinction has been made between the stoichiometric valence derived from chemical analysis and the structural valence derived from structure data.
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页码：589 / 591
页数：3
相关论文
共 11 条
[1]   BOND-VALENCE PARAMETERS FOR SOLIDS [J].
BRESE, NE ;
OKEEFFE, M .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 :192-197
[2]  
Brown I.D., 2002, CHEM BOND INORGANIC, DOI DOI 10.1093/ACPROF:OSO/9780198742951.001.0001
[3]  
Burns PC, 1997, CAN MINERAL, V35, P1551
[4]   Are the compressive effects of encapsulation an artifact of the bond valence parameters? [J].
Krivovichev, SV ;
Brown, ID .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2001, 216 (05) :245-247
[5]   A Re-Examination of the Bond Valence Model. [J].
Liebau, F. ;
Wang, X. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2004, 60 :S71-S71
[6]   Revised Tl(I)-O bond valence parameters and the structures of thallous dichromate and thallous uranyl phosphate hydrate [J].
Locock, AJ ;
Burns, PC .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2004, 219 (05) :259-266
[7]   A new relation between bond valence and bond distance [J].
Mohri, F .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2000, 56 (04) :626-638
[8]   The principles determining the structure of complex ionic crystals [J].
Pauling, L .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1929, 51 (1-4) :1010-1026
[9]   Influence of lone-pair electrons of cations on bond-valence parameters [J].
Wang, X ;
Liebau, F .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1996, 211 (07) :437-439
[10]  
WANG X, 2005, MAT RES SOC S P, V848
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