Adsorptive removal of chloramphenicol from wastewater by NaOH modified bamboo charcoal

被引:222
作者
Fan, Ye [1 ]
Wang, Bin [1 ]
Yuan, Songhu [1 ,2 ,3 ]
Wu, Xiaohui [1 ,2 ,3 ]
Chen, Jing [1 ]
Wang, Linling [1 ]
机构
[1] Huazhong Univ Sci & Technol, Environm Sci Res Inst, Wuhan 430074, Peoples R China
[2] S Cent Univ Nationalities, Key Lab Catalysis & Mat Sci, State Ethn Affairs Commiss, Wuhan 430074, Peoples R China
[3] S Cent Univ Nationalities, Minist Educ, Wuhan 430074, Peoples R China
关键词
Bamboo charcoal; Adsorption; Antibiotics; Wastewater; ACTIVATED CARBON; EQUILIBRIUM; CAPACITY; KINETICS; ANTIBIOTICS; NANOFIBERS;
D O I
10.1016/j.biortech.2010.04.046
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
This study described the adsorption of chloramphenicol (CAP) in wastewater on the renewable bioresource of bamboo charcoal (BC). Results showed that CAP adsorption on BC (Ln q(e) = 1.272 Ln C-e + 1.971) and H2SO4 modified BC (Ln q(e) = 1.851 Ln C-e + 0.659) were very slight, and on NaOH modified BC was significantly increased (Ln q(e) = 0.344 Ln C-e + 6.490). The adsorbents were characterized by N-2 adsorption-desorption, X-ray diffraction (XRD), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). It is revealed that BC and modified BC had very small surface areas of less than 1 m(2) g(-1), H2SO4 treatment led to minimal variation in surface functional groups, and NaOH treatment increased the percentage of surface graphitic carbon and other oxygen-containing groups. The increased adsorption of CAP on NaOH modified BC was mainly ascribed to the enhancement of the pi-pi interaction between the adsorbent and adsorbate. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:7661 / 7664
页数:4
相关论文
共 15 条
[1]   Effect of microwave and conventional regeneration on the microporous and mesoporous network and on the adsorptive capacity of activated carbons [J].
Ania, CO ;
Parra, JB ;
Menéndez, JA ;
Pis, JJ .
MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 85 (1-2) :7-15
[2]   Degree of functionalization of carbon nanofibers with benzenesulfonic groups in an acid medium [J].
Barroso-Bujans, F. ;
Fierro, J. L. G. ;
Rojas, S. ;
Sanchez-Cortes, S. ;
Arroyo, M. ;
Lopez-Manchado, M. A. .
CARBON, 2007, 45 (08) :1669-1678
[3]   Adsorption of methylene blue onto bamboo-based activated carbon: Kinetics and equilibrium studies [J].
Hameed, B. H. ;
Din, A. T. M. ;
Ahmad, A. L. .
JOURNAL OF HAZARDOUS MATERIALS, 2007, 141 (03) :819-825
[4]   Adsorption equilibrium of amino acids and antibiotics on non-ionic polymeric sorbents [J].
Lee, JW ;
Shim, WG ;
Yang, WC ;
Moon, H .
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2004, 79 (04) :413-420
[5]   Antibiotics and antibiotic resistance genes in natural environments [J].
Martinez, Jose L. .
SCIENCE, 2008, 321 (5887) :365-367
[6]   Adsorption Mechanisms of Organic Chemicals on Carbon Nanotubes [J].
Pan, Bo ;
Xing, Baoshan .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2008, 42 (24) :9005-9013
[7]   Activated carbons modified with sewage sludge derived phase and their application in the process of NO2 removal [J].
Pietrzak, Robert ;
Bandosz, Teresa J. .
CARBON, 2007, 45 (13) :2537-2546
[8]   Effect of modification with HNO3 and NaOH on metal adsorption by pitch-based activated carbon fibers [J].
Shim, JW ;
Park, SJ ;
Ryu, SK .
CARBON, 2001, 39 (11) :1635-1642
[9]   The effect of the gradual thermal decomposition of surface oxygen species on the chemical and catalytic properties of oxidized activated carbon [J].
Szymanski, GS ;
Karpinski, Z ;
Biniak, S ;
Swiatkowski, A .
CARBON, 2002, 40 (14) :2627-2639
[10]   XRD analysis of carbon stacking structure in coal during heat treatment [J].
Takagi, H ;
Maruyama, K ;
Yoshizawa, N ;
Yamada, Y ;
Sato, Y .
FUEL, 2004, 83 (17-18) :2427-2433