N,N-dialkylcarbamato complexes as precursors for the chemical implantation of metal cations on a silica support .1. Tin

被引：33
作者：
Abis, L
DellAmico, DB
Calderazzo, F
Caminiti, R
Garbassi, F
Ianelli, S
Pelizzi, G
Robino, P
Tomei, A
机构：
[1] UNIV PISA,DIPARTIMENTO CHIM & CHIM IND,SEZ CHIM INORGAN,I-56126 PISA,ITALY
[2] IST GUIDO DONEGANI ENICHEM,I-28100 NOVARA,ITALY
[3] UNIV ROMA LA SAPIENZA,DIPARTIMENTO CHIM,I-00185 ROME,ITALY
[4] UNIV PARMA,IST CHIM GEN,I-43100 PARMA,ITALY
[5] CNR,CTR STUDIO STRUTTURIST DIFFRATTOMETR,I-43100 PARMA,ITALY
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1996年 / 108卷 / 03期
关键词：
implantation; carbamate; tin; silica; N; N-dialkylcarbamates; SURFACE ORGANOMETALLIC CHEMISTRY; MOLECULAR-STRUCTURE; ALLYL RHODIUM; CRYSTAL; CATALYSIS; ALUMINA; SIO2; ACTIVATION; CARBONYLS; OS3(CO)12;
D O I：
10.1016/1381-1169(96)00032-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Chemical implantation of tin on a commercial silica has been carried out by using the hydrocarbon soluble Sn((O2CNPr2)-Pr-i)(4) as precursor, the N,N-dialkylcarbamato group is chemically displaced by the silanol groups of the support under mild conditions.
引用
收藏
页码：L113 / L117
页数：5
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