Copper-Catalyzed Synthesis of Triarylamines from Aryl Halides and Arylamines

被引：11

作者：

Qian Cunwei ^{[1
]}

Xu Shaojie ^{[1
]}

Zong Qianshou ^{[2
]}

Fang Dong ^{[1
]}

机构：

[1] Yancheng Teachers Univ, Sch Chem & Chem Engn, Yancheng 224051, Jiangsu, Peoples R China

[2] Jiaxing Univ, Sch Biol & Chem Engn, Jiaxing 314001, Zhejiang, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2012年 / 30卷 / 08期

关键词：

copper catalyst; Ullmann coupling; triphenylamine; synthesis; ROOM-TEMPERATURE AMINATION; N BOND FORMATION; C-N; COUPLING REACTIONS; ULLMANN SYNTHESIS; HIGHLY EFFICIENT; ARYLATION; AMINES; LIGAND; BROMIDES;

D O I：

10.1002/cjoc.201200247

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple and efficient methodology for the synthesis of triphenylamines has been demonstrated using copper catalyst with a ligand and tripotassium phosphate as the base. The effect of parameters such as catalyst precursors, ligands, bases and solvents were studied and a series of triphenylamines were obtained with moderate to excellent yields in DMF. This reaction displays great functional groups compatibility in the presence of a broad range of functional groups.

引用

页码：1881 / 1885

页数：5

共 50 条

[1] Synthesis of triarylamines by copper-catalyzed amination of aryl halides
Patil, NM
Kelkar, AA
Chaudhari, RV
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 223 (1-2) : 45 - 50
[2] Copper-catalyzed amination of aryl halides: single-step synthesis of triarylamines
Kelkar, AA
Patil, NM
Chaudhari, RV
TETRAHEDRON LETTERS, 2002, 43 (40) : 7143 - 7146
[3] Copper-catalyzed synthesis of primary arylamines from aryl halides and 2,2,2-trifluoroacetamide
Tao, Chuan-Zhou
Li, Juan
Fu, Yao
Liu, Lei
Guo, Qing-Xiang
TETRAHEDRON LETTERS, 2008, 49 (01) : 70 - 75
[4] Room-Temperature Copper-Catalyzed Synthesis of Primary Arylamines from Aryl Halides and Aqueous Ammonia
Tao, Chuanzhou
Liu, Weiwei
Lv, Aifeng
Sun, Mingming
Tian, Ying
Wang, Qi
Zhao, Jing
SYNLETT, 2010, (09) : 1355 - 1358
[5] Copper-catalyzed synthesis of primary arylamines via cascade reactions of aryl halides with amidine hydrochlorides
Gao, Xiaoting
Fu, Hua
Qiao, Renzhong
Jiang, Yuyang
Zhao, Yufen
JOURNAL OF ORGANIC CHEMISTRY, 2008, 73 (17): : 6864 - 6866
[6] Palladium-catalyzed synthesis of triarylamines from aryl halides and diarylamines
Yamamoto, T
Nishiyama, M
Koie, Y
TETRAHEDRON LETTERS, 1998, 39 (16) : 2367 - 2370
[7] Efficient copper-catalyzed amination from aryl chlorides to primary arylamines
Song, Ji-Hye
Yun, Taeil
Jeon, Heung Bae
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
[8] Copper-Catalyzed Regioselective Synthesis of N-Aryl Amides from Aldoximes and Aryl Halides
Panda, Niranjan
Mothkuri, Raghavender
Nayak, Dinesh Kumar
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2014, 2014 (08) : 1602 - 1605
[9] An Efficient Copper-Catalyzed Etherification of Aryl Halides
Huang, Jinkun
Chen, Ying
Chan, Johann
Ronk, Mike L.
Larsen, Robert D.
Faul, Margaret M.
SYNLETT, 2011, (10) : 1419 - 1422
[10] Copper-catalyzed direct preparation of phenols from aryl halides
Mehmood, Arshad
Leadbeater, Nicholas E.
CATALYSIS COMMUNICATIONS, 2010, 12 (01) : 64 - 66

← 1 2 3 4 5 →