NITROMETHANE IN POLYPHOSPHORIC ACID-A NEW REAGENT FOR CARBOXYAMIDATION AND CARBOXYLATION OF ACTIVATED AROMATIC COMPOUNDS

被引：14

作者：

Aksenov, Alexander V. ^{[1
]}

Aksenov, Nicolai A. ^{[1
]}

Nadein, Oleg N. ^{[1
]}

Aksenova, Inna V. ^{[1
]}

机构：

[1] Stavropol State Univ, Stavropol 355009, Russia

来源：

SYNTHETIC COMMUNICATIONS | 2012年 / 42卷 / 04期

关键词：

Aromatic compounds; carboxyamidation; carboxylation; nitromethane; polyphosphoric acid; AMIDES; DERIVATIVES; OXIDATION; ALDEHYDES; SECONDARY; NITRILES;

D O I：

10.1080/00397911.2010.526284

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new method of carboxyamidation of aromatic compounds based on their reaction with nitromethane in polyphosphoric acid has been developed. Upon the hydrolysis of benzamides during the reaction mixture workup, the corresponding benzoic acids can be obtained.

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页码：541 / 547

页数：7

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