Synthesis, crystal structures and biological activities of transition metal complexes of a salen-type ligand

被引：9

作者：

Bendre, Ratnamala S. ^{[1
]}

Tadavi, Samina K. ^{[1
]}

Patil, Manohar M. ^{[1
]}

机构：

[1] North Maharashtra Univ, Sch Chem Sci, Jalgaon 425001, Maharashtra, India

来源：

TRANSITION METAL CHEMISTRY | 2018年 / 43卷 / 01期

关键词：

SCHIFF-BASE; COPPER(II) COMPLEXES; MANGANESE(III); NICKEL(II); COBALT(II); ZN(II); NI(II); DNA;

D O I：

10.1007/s11243-017-0196-y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Manganese(III), cobalt(II), nickel(II) and copper(II) complexes of a salen-type ligand, namely 6,6'-((1E,1'E)-(ethane-1,2-diylbis(azanylylidene))bis(methanylylidene))bis(5-isopropyl-2-methylphenol) (H2L), have been synthesized and characterized by physicochemical and spectroscopic methods. In addition, single-crystal X-ray analysis confirmed the formulae of the manganese and nickel complexes as [Mn(OAc)(L)] and [Ni(L)], respectively. The free Schiff base and its complexes have been screened for in vitro antibacterial activity by colony count methods, and the antioxidant activity was assayed by DPPH radical scavenging. The ability of free H2L and its complexes to mediate DNA cleavage was studied by agarose gel electrophoresis.

引用

页码：83 / 89

页数：7

共 50 条

[41] Novel Cyclic Schiff Base and Its Transition Metal Complexes: Synthesis, Spectral and Biological Investigations [J].

Aggarwal, Pallvi ;

Tuli, Singh Hardeep ;

Kumar, Manoj .

IRANIAN JOURNAL OF CHEMISTRY & CHEMICAL ENGINEERING-INTERNATIONAL ENGLISH EDITION, 2022, 41 (02) :417-430

[42] Synthesis and crystal structure of some transition metal complexes with a novel bis-Schiff base ligand and their antitumor activities [J].

Zhong, X. ;

Yi, J. ;

Sun, J. ;

Wei, H. -L. ;

Liu, W. -S. ;

Yu, K. -B. .

EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2006, 41 (09) :1090-1092

[43] Exploration on Synthesis, Characterization and Biological Activities of Transition Metal Complexes Comprising Hydroxybenzylideneaminocyclohexylimino-methyl-4,6-dibromophenol Schiff Base Ligand [J].

Manimalathi, S. ;

Priya, J. ;

Madheswari, D. .

ARABIAN JOURNAL FOR SCIENCE AND ENGINEERING, 2024, 49 (07) :9691-9711

[44] Synthesis, Spectral Characterization, and Biological Activities of Some Metal Complexes Bearing an Unsymmetrical Salen-Type Ligand, (Z)-1-(((2-((E)-(2-Hydroxy-6-methoxybenzylidene)amino)phenyl)amino) methylene) Naphthalen-2(1H)-one [J].

Nguyen, Quang Trung ;

Thi, Phuong Nam Pham ;

Bui, Quang Do ;

Nguyen, Van Tuyen .

HETEROATOM CHEMISTRY, 2023, 2023

[45] Synthesis and crystal structures of salen-type Cu(ii) and Ni(ii) Schiff base complexes: application in [3+2]-cycloaddition and A3-coupling reactions [J].

Agrahari, Bhumika ;

Layek, Samaresh ;

Ganguly, Rakesh ;

Pathak, Devendra D. .

NEW JOURNAL OF CHEMISTRY, 2018, 42 (16) :13754-13762

[46] The transition metal complexes of Fe(II), Ni(II) and Cu(II) derived from phthalazine based ligands: Synthesis, crystal structures and biological activities [J].

Patil, Smita S. ;

Tadavi, Samina K. ;

Dikundwar, Amol ;

Bendre, Ratnamala S. .

JOURNAL OF MOLECULAR STRUCTURE, 2022, 1247

[47] Synthesis, Spectral, Electrochemical and Biological Studies of Nitrogen Donor Macrocyclic Ligand and its Transition Metal Complexes [J].

Shiekh, Rayees Ahmad ;

Ab Rahman, Ismail ;

Malik, Maqsood Ahmad ;

Masudi, Sam'an Malik ;

Luddin, Norhayati .

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2012, 7 (12) :12829-12845

[48] Spectroscopic, thermal analysis and DFT computational studies of salen-type Schiff base complexes [J].

Ebrahimi, Hossein Pasha ;

Hadi, Jabbar S. ;

Abdulnabi, Zuhair A. ;

Bolandnazar, Zeinab .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2014, 117 :485-492

[49] A new Salen-type azo-azomethine ligand and its Ni(II), Cu(II) and Zn(II) complexes: Synthesis, spectral characterization, crystal structure and photoluminescence studies [J].

Ozkan, Gozde ;

Kose, Muhammet ;

Zengin, Huseyin ;

McKee, Vickie ;

Kurtoglu, Mukerrem .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2015, 150 :966-973

[50] Two mononuclear nickel(II) complexes with Schiff base ligands: Synthesis, crystal structures, and antibacterial activities [J].

Sun, Wei-Hang ;

Wu, Lu-Lu ;

Ye, Lei ;

Xin, Yu ;

Zhang, Yan ;

Liu, Hui ;

Lv, Kai-Wen ;

Shang, Chao-Nan ;

You, Zhonglu ;

Li, Wei .

INORGANIC AND NANO-METAL CHEMISTRY, 2017, 47 (10) :1385-1391

← 1 2 3 4 5 →