Effects of various surface treatments on Aloe Vera fibers used as reinforcement in poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBHHx) biocomposites

被引：33
作者：
Dehouche, Nadjet [1 ]
Idres, Celia [1 ]
Kaci, Mustapha [1 ]
Zembouai, Idris [1 ]
Bruzaud, Stephane [2 ]
机构：
[1] Univ Bejaia, LMPA, Bejaia 06000, Algeria
[2] Univ Bretagne Sud, CNRS, UMR 6027, IRDL, Rue St Maude, F-56321 Lorient, France
来源：
POLYMER DEGRADATION AND STABILITY | 2020年 / 175卷
关键词：
PHBHHx; Aloe Vera fibers (AVF); Biocomposites; Fiber surface treatment; Morphology; MECHANICAL-PROPERTIES; CRYSTALLIZATION BEHAVIOR; CELLULOSE FIBERS; SILANE TREATMENT; HUSK FLOUR; COMPOSITES; MORPHOLOGY; FILLER; HEMP;
D O I：
10.1016/j.polymdegradstab.2020.109131
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The aim of this study was to assess the effect of various surface treatments on Aloe Vera fibers (AVF) used as reinforcement in PHBHHx biocomposites prepared by melt compounding. AVF were subjected to various surface treatments including alkaline, organo-silanes and combined alkaline/organo-silanes treatments. Both untreated and treated AVF were added to PHBHHx at filler content of 20 wt% and the resulted biocomposites were characterized using scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), water absorption test and rheological measurements. The study showed that the combined alkaline/organo-silanes treatment of AVF resulted in better morphology and properties of PHBHHx biocomposite compared to untreated AVF and those treated either with alkaline or with organosilanes. Indeed, SEM analysis of the fracture surface of PHBHHx/AVF treated with combined alkaline-organosilanes showed better fiber-matrix interactions compared to the other samples. As a result, rheological properties, i.e., complex viscosity (eta*), storage modulus (G') and loss modulus (G '') were increased. Higher resistance to water absorption was observed for PHBHHx/AVF treated with combined alkaline-organosilanes. Whereas, the various surface fiber treatments led to no noticeable change in thermal characteristics of the biocomposites. This study highlights the effectiveness of combined alkaline/organo-silanes treatment of AVF over alkaline and organo-silanes and their applications in PHBHHx biocomposites as an interesting source of cellulosic reinforcing materials. (C) 2020 Elsevier Ltd. All rights reserved.
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页数：10
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