CO-retentive addition reactions of fluorinated acid chlorides to alkynes

被引：39

作者：

Kashiwabara, T ^{[1
]}

Kataoka, K

Hua, R

Shimada, S

Tanaka, M

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

[2] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China

[3] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 11期

关键词：

D O I：

10.1021/ol050632w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of perfluorinated acid chlorides with terminal alkynes is efficiently catalyzed by rhodium complexes and proceeds with retention of the CO moiety in the acid chloride to afford (2)-1-perfluoroacyl-2-chloro-1-alkenes selectively in high yields.

引用

页码：2241 / 2244

页数：4

共 27 条

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