A novel inorganic-organic compound:: Synthesis and structural characterization of tin(II) phenylbis(phosphonate), Sn2(PO3C6H4PO3)

被引：11
作者：
Subbiah, A [1 ]
Bhuvanesh, N [1 ]
Clearfield, A [1 ]
机构：
[1] Texas A&M Univ, Dept Chem, Clearfield Res Grp, TAMU 3255,POB 30012, College Stn, TX 77842 USA
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2005年 / 178卷 / 04期
基金：
美国国家科学基金会;
关键词：
inorganic-organic hybrid; hydrothermal synthesis;
D O I：
10.1016/j.jssc.2005.02.004
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel tin(II) phenylbis(phosphonate) compound has been synthesized hydrothermally and its structure has been determined by single crystal X-ray diffraction. The structure is monoclinic, space group P2(1)/c (no. 14), a = 4.8094(4), b = 16.2871(13), c = 6.9107(6) angstrom, beta = 106.292(6)degrees, V = 519.59(7) angstrom(3), Z = 2. The three-dimensional structure consists of 3-coordinated tin and 4-coordinated phosphorus double layers separated (pillared) by phenyl rings. These phenyl rings are placed 4.8 angstrom apart along the a-axis in the structure resulting in lower surface area (similar to 14m(2)/g). The porosity has been increased by replacing phenyl groups by methyl groups (similar to 31 m(2)/g). (c) 2005 Elsevier Inc. All rights reserved.
引用
收藏
页码：1321 / 1325
页数：5
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