Application of ferrocene-bridged N-heterocyclic carbene stabilised bis-phosphinidenes in Sn(ii) complexation

被引：8
|
作者：
Baierl, Ramona
Kostenko, Arseni
Hanusch, Franziska
Inoue, Shigeyoshi [1 ]
机构：
[1] Tech Univ Munich, Catalysis Res Ctr, Dept Chem, Lichtenbergstr 4, D-85748 Garching, Germany
来源：
DALTON TRANSACTIONS | 2021年 / 50卷 / 41期
关键词：
CATALYTIC APPLICATIONS; CATIONS; STANNYLENES; LIGANDS;
D O I：
10.1039/d1dt03016g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new bidentate ferrocene-bridged bis(N-heterocyclic carbene-phospinidenes) (bisNHCPs) were successfully isolated by treating 1,1 '-bis-(dichlorophosphine)ferrocene with N-heterocyclic carbenes, followed by dechlorination using sodium naphthalenide. The bisNHCPs were used in complexation of various Sn(ii) halides and Sn(ii) bistriflate (SnX2 with X = Cl, Br, I, OTf). Transmetalation to a CuCl complex and Sn(ii) transfer to a bisimine was performed to investigate the stannyliumylidenes' reactivity.
引用
收藏
页码：14842 / 14848
页数：7
相关论文
共 50 条
  • [21] Spin transitions in bis(amidinato)-N-heterocyclic carbene iron(II) and iron(III) complexes
    Drake, Jessica L.
    Kaplan, Hilan Z.
    Wilding, Matthew J. T.
    Li, Bo
    Byers, Jeffery A.
    DALTON TRANSACTIONS, 2015, 44 (38) : 16703 - 16707
  • [22] Density functional theory study of bis(imino) N-heterocyclic carbene iron(II) complexes
    Al Thagfi, Jameel
    Lavoie, Gino G.
    CANADIAN JOURNAL OF CHEMISTRY, 2014, 92 (10) : 925 - 931
  • [23] Novel ruthenium(II)-N-heterocyclic carbene complexes; synthesis, characterization and catalytic application
    Yasar, Sedat
    Karaca, Emine Ozge
    Sahin, Caglar
    Ozdemir, Ismail
    Sahin, Onur
    Buyukgungor, Orhan
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2015, 789-790 : 1 - 7
  • [24] Mono- and dinuclear Hg(II) complexes of bis-(N-heterocyclic carbene) bridged with calixarene fragments: Synthesis, structure and sensing behavior
    Lin, Cai-Xia
    Guo, Lin
    Li, Qing-Shan
    Zhang, Zheng-Zhi
    Yuan, Yao-Feng
    Xu, Feng-Bo
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2014, 749 : 180 - 187
  • [25] Copper(II) complexes of a heterotopic N-heterocyclic carbene ligand: Preparation and catalytic application
    Lin, Shih-Chieh Aaron
    Liu, Yi-Hung
    Peng, Shie-Ming
    Liu, Shiuh-Tzung
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 859 : 52 - 57
  • [26] N,N′-Bisaryl Substituted Chiral Linker -Bridged Bis(N-Heterocyclic Carbene) Palladium Complexes: Design, Synthesis, and Catalytic Properties
    Tang, Junkai
    He, Yu
    Yu, Jianfeng
    Zhang, Dao
    ORGANOMETALLICS, 2017, 36 (07) : 1372 - 1382
  • [27] New bimetallic complexes of late transition metals involving pyrazole-bridged bis N-heterocyclic carbene ligands
    Jeon, Sang-Jin
    Waymouth, Robert M.
    DALTON TRANSACTIONS, 2008, 8 (04) : 437 - 439
  • [28] Dinuclear Macrocyclic Quinoline Bridged Mercury and Silver Bis(N-heterocyclic Carbene) Complexes: Synthesis, Structure, and Spectroscopic Studies
    Lin, Cai-Xia
    Kong, Xiao-Fei
    Xu, Feng-Bo
    Zhang, Zheng-Zhi
    Yuan, Yao-Feng
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2013, 639 (06): : 881 - 885
  • [29] Nickel(II) Complex with the Bis(phenolate) Pincer N-Heterocyclic Carbene Ligand: Synthesis, Structure, and Properties
    Gafurov, Z. N.
    Mikhailov, I. K.
    Kagilev, A. A.
    Sakhapov, I. F.
    Kantyukov, A. O.
    Zueva, E. M.
    Dobrynin, A. B.
    Trifonov, A. A.
    Yakhvarov, D. G.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2024, 50 (10) : 769 - 777
  • [30] An Antitumor Bis(N-Heterocyclic Carbene)Platinum(II) Complex That Engages Asparagine Synthetase as an Anticancer Target
    Hu, Di
    Yang, Chen
    Lok, Chun-Nam
    Xing, Fangrong
    Lee, Pui-Yan
    Fung, Yi Man Eva
    Jiang, Haibo
    Che, Chi-Ming
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (32) : 10914 - 10918
12345