Application of ferrocene-bridged N-heterocyclic carbene stabilised bis-phosphinidenes in Sn(ii) complexation

被引：8
|
作者：
Baierl, Ramona
Kostenko, Arseni
Hanusch, Franziska
Inoue, Shigeyoshi [1 ]
机构：
[1] Tech Univ Munich, Catalysis Res Ctr, Dept Chem, Lichtenbergstr 4, D-85748 Garching, Germany
来源：
DALTON TRANSACTIONS | 2021年 / 50卷 / 41期
关键词：
CATALYTIC APPLICATIONS; CATIONS; STANNYLENES; LIGANDS;
D O I：
10.1039/d1dt03016g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new bidentate ferrocene-bridged bis(N-heterocyclic carbene-phospinidenes) (bisNHCPs) were successfully isolated by treating 1,1 '-bis-(dichlorophosphine)ferrocene with N-heterocyclic carbenes, followed by dechlorination using sodium naphthalenide. The bisNHCPs were used in complexation of various Sn(ii) halides and Sn(ii) bistriflate (SnX2 with X = Cl, Br, I, OTf). Transmetalation to a CuCl complex and Sn(ii) transfer to a bisimine was performed to investigate the stannyliumylidenes' reactivity.
引用
收藏
页码：14842 / 14848
页数：7
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