Deep Eutectic Solvents as Efficient Catalysts for Fixation of CO2 to Cyclic Carbonates at Ambient Temperature and Pressure through Synergetic Catalysis

被引：79
作者：
Yang, Xiaoqing [1 ]
Zou, Qizhuang [1 ]
Zhao, Tianxiang [1 ]
Chen, Peng [1 ]
Liu, Zimin [1 ]
Liu, Fei [1 ]
Lin, Qian [1 ]
机构：
[1] Guizhou Univ, Sch Chem & Chem Engn, Key Lab Green Chem & Clean Energy Technol, Guiyang 550025, Peoples R China
来源：
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2021年 / 9卷 / 31期
关键词：
Carbon dioxide; Deep eutectic solvents; Cyclic carbonates; Ionic liquids; Synergetic catalysis; PROTIC IONIC LIQUIDS; EPOXIDES; CONVERSION; TRANSFORMATION; ABSORPTION; ACTIVATION; DIOXIDE;
D O I：
10.1021/acssuschemeng.1c03187
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of deep eutectic solvents (DESs), consisting of protic ionic liquids (PILs) and amines, feature effective catalytic activity for the fixation of CO2 to cyclic carbonates at ambient temperature and pressure without any solvents and additives. Good yields of cyclic carbonates are achieved (up to 99%), and no obvious deactivation in catalytic activity is found after five cycles. Mechanistic research reveals that CO2 and epoxides are activated simultaneously through the synergistic catalysis of PILs and amines.
引用
收藏
页码：10437 / 10443
页数：7
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