Synthesis of an ionic liquid with an iron coordination cation

被引：48

作者：

Anderson, Travis M. ^{[1
]}

Ingersoll, David ^{[1
]}

Rose, Alyssa J. ^{[1
]}

Staiger, Chad L. ^{[1
]}

Leonard, Jonathan C. ^{[1
]}

机构：

[1] Sandia Natl Labs, Albuquerque, NM 87185 USA

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 37期

关键词：

ANION;

D O I：

10.1039/c0dt00523a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An iron-based ionic liquid, Fe((OHCH2CH2)(2)NH)(6)-(CF3SO3)(3), is synthesized in a single-step complexation reaction. Infrared and Raman data suggest NH(CH2CH2OH)(2) primarily coordinates to Fe(III) through alcohol groups. The compound has T-g and T-d values of -64 degrees C and 260 degrees C, respectively. Cyclic voltammetry reveals quasi-reversible Fe(III)/Fe(II) reduction waves.

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收藏

页码：8609 / 8612

页数：4

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