Metal-Organic Frameworks as Supramolecular Templates for Directing Aromatic Packing Motifs

被引：9

作者：

Lifshits, Liubov M. ^{[1
]}

Zeller, Matthias ^{[2
]}

Campana, Charles F. ^{[3
]}

Klosterman, Jeremy K. ^{[1
,4
]}

机构：

[1] Bowling Green State Univ, Dept Chem, Ctr Photochem Sci, Bowling Green, OH 43403 USA

[2] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA

[3] Bruker AXS Inc, Madison, WI 53711 USA

[4] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

CRYSTAL GROWTH & DESIGN | 2017年 / 17卷 / 10期

基金：

美国国家科学基金会;

关键词：

ENERGY-TRANSFER; CHARGE-TRANSFER; TRANSPORT; DESIGN; PHOTODIMERIZATION; ANTHRACENES; COMPLEXES; OLIGOMERS; ACRIDINE; CAPTURE;

D O I：

10.1021/acs.cgd.7b00954

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Modular methods to direct the molecular packing of aromatic organic chromophores are essential for understanding the subtle principles needed to predict intermolecular interactions and design uniform, efficient organic optoelectronic devices. Here we demonstrate that layered two-dimensional metal organic frameworks, based on the copper paddlewheel and 5-aryl isophthalate ligands, can alter the interstitial packing of the aryl groups and template new packing motifs for the small acenes.

引用

页码：5449 / 5457

页数：9

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