Phosphoryl azides as versatile new reaction partners in the Cu-catalyzed three-component couplings

被引：58
|
作者：
Kim, Seok Hwan [1 ]
Jung, Doo Young [1 ]
Chang, Sukbok [1 ]
机构：
[1] Korea Adv Inst Sci & Technol, Dept Chem, Sch Mol Sci, Ctr Mol Design & Synth, Taejon 305701, South Korea
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 72卷 / 25期
关键词：
D O I：
10.1021/jo7016247
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] Phosphoryl azide was successfully employed as an efficient reacting partner in the Cu-catalyzed three-component reaction with 1-alkynes and amines to produce the corresponding phosphoryl amidines in high yields. A range of fruitful applicability of the produced amidines was also demonstrated such as an alkoxide exchange and asymmetric alpha-alkylation of optically active BINOL-derived amidines.
引用
收藏
页码：9769 / 9771
页数：3
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