Phosphoryl azides as versatile new reaction partners in the Cu-catalyzed three-component couplings

被引：58

作者：

Kim, Seok Hwan ^{[1
]}

Jung, Doo Young ^{[1
]}

Chang, Sukbok ^{[1
]}

机构：

[1] Korea Adv Inst Sci & Technol, Dept Chem, Sch Mol Sci, Ctr Mol Design & Synth, Taejon 305701, South Korea

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 72卷 / 25期

关键词：

D O I：

10.1021/jo7016247

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Phosphoryl azide was successfully employed as an efficient reacting partner in the Cu-catalyzed three-component reaction with 1-alkynes and amines to produce the corresponding phosphoryl amidines in high yields. A range of fruitful applicability of the produced amidines was also demonstrated such as an alkoxide exchange and asymmetric alpha-alkylation of optically active BINOL-derived amidines.

引用

页码：9769 / 9771

页数：3

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