Phosphoryl azides as versatile new reaction partners in the Cu-catalyzed three-component couplings
被引:58
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作者:
Kim, Seok Hwan
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机构:
Korea Adv Inst Sci & Technol, Dept Chem, Sch Mol Sci, Ctr Mol Design & Synth, Taejon 305701, South KoreaKorea Adv Inst Sci & Technol, Dept Chem, Sch Mol Sci, Ctr Mol Design & Synth, Taejon 305701, South Korea
Kim, Seok Hwan
[1
]
Jung, Doo Young
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h-index: 0
机构:
Korea Adv Inst Sci & Technol, Dept Chem, Sch Mol Sci, Ctr Mol Design & Synth, Taejon 305701, South KoreaKorea Adv Inst Sci & Technol, Dept Chem, Sch Mol Sci, Ctr Mol Design & Synth, Taejon 305701, South Korea
Jung, Doo Young
[1
]
Chang, Sukbok
论文数: 0引用数: 0
h-index: 0
机构:
Korea Adv Inst Sci & Technol, Dept Chem, Sch Mol Sci, Ctr Mol Design & Synth, Taejon 305701, South KoreaKorea Adv Inst Sci & Technol, Dept Chem, Sch Mol Sci, Ctr Mol Design & Synth, Taejon 305701, South Korea
Chang, Sukbok
[1
]
机构:
[1] Korea Adv Inst Sci & Technol, Dept Chem, Sch Mol Sci, Ctr Mol Design & Synth, Taejon 305701, South Korea
来源:
JOURNAL OF ORGANIC CHEMISTRY
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2007年
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72卷
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25期
关键词:
D O I:
10.1021/jo7016247
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
[GRAPHICS] Phosphoryl azide was successfully employed as an efficient reacting partner in the Cu-catalyzed three-component reaction with 1-alkynes and amines to produce the corresponding phosphoryl amidines in high yields. A range of fruitful applicability of the produced amidines was also demonstrated such as an alkoxide exchange and asymmetric alpha-alkylation of optically active BINOL-derived amidines.