Microstructure and crystallization properties of Na2O-CaO-SiO2 glass system with different ZrO2 content

被引：13

作者：

Chen, Baoxi ^{[1
]}

Han, Na ^{[2
]}

Cao, Xin ^{[2
]}

Guo, Yunlan ^{[1
]}

Liu, Chao ^{[1
]}

机构：

[1] Wuhan Univ Technol, State Key Lab Silicate Mat Architectures SMART, Wuhan 430070, Peoples R China

[2] CNBM Bengbu Design & Res Inst Glass Ind Co Ltd, State Key Lab Adv Technol Float Glass, Bengbu, Peoples R China

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 2021年 / 573卷

关键词：

Na2O-CaO-SiO; Glass-ceramics; ZrO2; Glass structure; Vickers hardness; X-RAY-DIFFRACTION; LITHIUM DISILICATE GLASS; LI2O-AL2O3-SIO2; GLASS; MECHANICAL-PROPERTIES; SILICATE-GLASSES; CRYSTAL-GROWTH; ZIRCON ZRSIO4; RAMAN; TRANSPARENT; CERAMICS;

D O I：

10.1016/j.jnoncrysol.2021.121137

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Glass-ceramics based on Na2O-CaO-SiO2 system show attractive properties due to the high transparency even with large crystals size. In this work, effects of ZrO2 on glass structure and crystallization behaviors of Na2O-CaOSiO2 glasses were investigated. The introduction of ZrO2 has significant influence on glass network and resultant thermal and crystallization properties. Glass transition temperature and first crystallization temperature increase monotonically with the increase of ZrO2 content. In addition to Na4Ca4(Si6O18) crystalline phase, Na4Zr2(SiO4)3 and Na2ZrSi2O7 crystalline phases are precipitated when the content of ZrO2 is high. Vickers hardness of the asprepared and heat-treated glass increases significantly with the increase of ZrO2 content and heat-treatment temperature.

引用

页数：7

共 42 条

[1] Raman and NMR study of bioactive Na2O-MgO-CaO-P2O5-SiO2 glasses [J].

Aguiar, H. ;

Solla, E. L. ;

Serra, J. ;

Gonzalez, P. ;

Leon, B. ;

Malz, F. ;

Jaeger, C. .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2008, 354 (45-46) :5004-5008

[2] Nanophase glass-ceramics [J].

Beall, GH ;

Pinckney, LR .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1999, 82 (01) :5-16

[3] Structure and mechanical properties of compressed sodium aluminosilicate glasses: Role of non-bridging oxygens [J].

Bechgaard, Tobias K. ;

Goel, Ashutosh ;

Youngman, Randall E. ;

Mauro, John C. ;

Rzoska, Sylwester J. ;

Bockowski, Michal ;

Jensen, Lars R. ;

Smedskjaer, Morten M. .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2016, 441 :49-57

[4] In situ Raman spectroscopy investigation of bioactive glass reactivity: Simulated body fluid solution vs TRIS-buffered solution [J].

Bellucci, D. ;

Bolelli, G. ;

Cannillo, V. ;

Cattini, A. ;

Sola, A. .

MATERIALS CHARACTERIZATION, 2011, 62 (10) :1021-1028

[5] New large grain, highly crystalline, transparent glass-ceramics [J].

Berthier, Thiana ;

Fokin, Vladimir M. ;

Zanotto, Edgar D. .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2008, 354 (15-16) :1721-1730

[6] Glass ceramics of high hardness and fracture toughness developed from steel fly ash [J].

Boccaccini, A. R. ;

Han, W. X. ;

Dimech, C. ;

Rawlings, R. D. .

MATERIALS SCIENCE AND TECHNOLOGY, 2006, 22 (10) :1148-1154

[7] Full and ideal mixing behavior between Zr-Wd (K2ZrSi3O9) and Ti-Wd (K2TiSi3O9): evidences from mineral chemistry, X-ray diffraction pattern and Raman spectrum [J].

Chang, Linlin ;

Liu, Xi ;

Wu, Chunming ;

Liu, Xiaoyang ;

Li, Guowu .

PHYSICS AND CHEMISTRY OF MINERALS, 2015, 42 (03) :223-234

[8] The structural role of Zr within alkali borosilicate glasses for nuclear waste immobilisation [J].

Connelly, A. J. ;

Hyatt, N. C. ;

Travis, K. P. ;

Hand, R. J. ;

Maddrell, E. R. ;

Short, R. J. .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2011, 357 (07) :1647-1656

[9] METHODS FOR IMPROVING THE MECHANICAL-PROPERTIES OF OXIDE GLASSES [J].

DONALD, IW .

JOURNAL OF MATERIALS SCIENCE, 1989, 24 (12) :4177-4208

[10] Soda lime zirconia silicate glasses as prospective hosts for zirconia-containing radioactive wastes [J].

Fisher, JG ;

James, PF ;

Parker, JM .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2005, 351 (8-9) :623-631

← 1 2 3 4 5 →