Neodymium versatate catalyst for the 1,3-butadiene polymerization - Effects of reaction parameters

被引：7

作者：

Gaioto, Carolina C. ^{[1
]}

Schmal, Martin ^{[1
]}

da Silva Pinto, Jose Carlos ^{[1
]}

机构：

[1] Univ Fed Rio de Janeiro, COPPE, Programa Engn Quim, Cidade Univ,CP 68502, BR-21941972 Rio De Janeiro, RJ, Brazil

来源：

CATALYSIS TODAY | 2020年 / 344卷

关键词：

1,3-Butadiene; Polybutadiene; Solution polymerization; Neodymium catalyst; ZIEGLER-NATTA CATALYST; HIGH CIS-POLYBUTADIENE; BUTADIENE; SESQUICHLORIDE; OPTIMIZATION;

D O I：

10.1016/j.cattod.2018.10.031

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Neodymium versatate was used as catalyst to perform solution 1,3-butadiene polymerizations. Catalysts were synthesized and aged at 5 degrees C for 0-60 days. Reactions were performed in the temperature range from 60 to 80 degrees C for 40-120 min. The obtained polymer products were characterized by Fourier-transform infrared spectroscopy (FTIR) and gel permeation chromatography (GPC). It is shown that the isomers content of the final resin is sensitive to ageing and to modification of the reaction temperature in the analyzed range. Besides, aged catalysts allowed for production of polybutadienes with higher molecular weights and higher polymer yields. Finally, it is shown that chain reincorporation reactions take place when reaction is allowed to continue after reaching monomer conversions that are close to 100%.

引用

页码：84 / 91

页数：8

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