Synthesis of Blue-Luminescent Seven-Membered Phosphorus Heterocycles

被引：23
作者：
Regulska, Elzbieta [1 ]
Ruppert, Heiko [1 ]
Rominger, Frank [1 ]
Romero-Nieto, Carlos [1 ,2 ]
机构：
[1] Heidelberg Univ, Organisch Chem Inst, Neuenheimer Feld 270, D-69120 Heidelberg, Germany
[2] Univ Castilla La Mancha, Fac Pharm, Calle Almansa 14 Edif Bioincubadora, Albacete 02008, Spain
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 85卷 / 02期
关键词：
ORGANOPHOSPHORUS; FLUORESCENCE; DERIVATIVES; LIGANDS; DESIGN;
D O I：
10.1021/acs.joc.9b02723
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A facile synthetic procedure to prepare pi-extended seven-membered phosphorus heterocycles, both symmetric and asymmetric, is reported. The prepared molecules present a persistent nonplanar framework and are soluble in a wide variety of solvents. The seven-membered phosphorus heterocycles can be electrochemically reduced and oxidized, and photoluminesce with a blue color.
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收藏
页码：1247 / 1252
页数：6
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