An unprecedented triply interpenetrated chiral network of 'square-planar' metal centres from the self-assembly of copper(II) nitrate and 1,2-bis(4-pyridyl)ethyne

被引：245

作者：

Carlucci, L

Ciani, G

Macchi, P

Proserpio, DM

机构：

[1] Dipartimento Chim Strutturale & Stereochim Inorga, I-20133 Milan, Italy

[2] Ctr CNR, I-20133 Milan, Italy

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 17期

关键词：

D O I：

10.1039/a803662d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper(II) nitrate reacts with 1,2-bis(4-pyridyl)ethyne (bpethy) in ethanol to yield mixtures containing, beside to a one-dimensional ladder-like polymer, a networked [Cu(bpethy)(2)] species, with a triply interpenetrated chiral frame based on pseudo-square planar metal centres, showing a topology theoretically predicted but never observed before, and containing uncoordinated ligands as guest molecules.

引用

收藏

页码：1837 / 1838

页数：2

相关论文

共 23 条

[1] SIR92 - a program for automatic solution of crystal structures by direct methods [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, G ;

GUAGLIARDI, A ;

BURLA, MC ;

POLIDORI, G ;

CAMALLI, M .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435

[2] Control of interpenetrating copper(I) adamantoid networks: Synthesis and structure of {[Cu(bpe)(2)]BF4}(n) [J].

Blake, AJ ;

Champness, NR ;

Chung, SSM ;

Li, WS ;

Schroder, M .

CHEMICAL COMMUNICATIONS, 1997, (11) :1005-1006

[3] Polycatenated copper(I) molecular ladders: a new structural motif in inorganic coordination polymers [J].

Blake, AJ ;

Champness, NR ;

Khlobystov, A ;

Lemenovskii, DA ;

Li, WS ;

Schroder, M .

CHEMICAL COMMUNICATIONS, 1997, (21) :2027-2028

[4] Self-assembly of infinite double helical and tubular coordination polymers from Ag(CF3SO3) and 1,3-bis(4-pyridyl)propane [J].

Carlucci, L ;

Ciani, G ;

vonGudenberg, DW ;

Proserpio, DM .

INORGANIC CHEMISTRY, 1997, 36 (18) :3812-3813

[5] INTERPENETRATING DIAMONDOID FRAMEWORKS OF SILVER(I) CATIONS LINKED BY N,N'-BIDENTATE MOLECULAR RODS [J].

CARLUCCI, L ;

CIANI, G ;

PROSERPIO, DM ;

SIRONI, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (24) :2755-2756

[6] ON ENANTIOMORPH-POLARITY ESTIMATION [J].

FLACK, HD .

ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881

[7] PREPARATION, CLATHRATION ABILITY, AND CATALYSIS OF A 2-DIMENSIONAL SQUARE NETWORK MATERIAL COMPOSED OF CADMIUM(II) AND 4,4'-BIPYRIDINE [J].

FUJITA, M ;

KWON, YJ ;

WASHIZU, S ;

OGURA, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (03) :1151-1152

[8] INTERPENETRATING MOLECULAR LADDERS AND BRICKS [J].

FUJITA, M ;

KWON, YJ ;

SASAKI, O ;

YAMAGUCHI, K ;

OGURA, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (27) :7287-7288

[9] A NEW TYPE OF INTERPENETRATION INVOLVING ENMESHED INDEPENDENT SQUARE GRID SHEETS - THE STRUCTURE OF DIAQUABIS-(4,4'-BIPYRIDINE)ZINC HEXAFLUOROSILICATE [J].

GABLE, RW ;

HOSKINS, BF ;

ROBSON, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (23) :1677-1678

[10] Supramolecular isomerism in coordination polymers: Conformational freedom of ligands in [Co(NO3)(2)(1,2-bis(4-pyridyl)ethane)(1.5)](n) [J].

Hennigar, TL ;

MacQuarrie, DC ;

Losier, P ;

Rogers, RD ;

Zaworotko, MJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (09) :972-973