An unprecedented triply interpenetrated chiral network of 'square-planar' metal centres from the self-assembly of copper(II) nitrate and 1,2-bis(4-pyridyl)ethyne

被引：245
作者：
Carlucci, L
Ciani, G
Macchi, P
Proserpio, DM
机构：
[1] Dipartimento Chim Strutturale & Stereochim Inorga, I-20133 Milan, Italy
[2] Ctr CNR, I-20133 Milan, Italy
来源：
CHEMICAL COMMUNICATIONS | 1998年 / 17期
关键词：
D O I：
10.1039/a803662d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Copper(II) nitrate reacts with 1,2-bis(4-pyridyl)ethyne (bpethy) in ethanol to yield mixtures containing, beside to a one-dimensional ladder-like polymer, a networked [Cu(bpethy)(2)] species, with a triply interpenetrated chiral frame based on pseudo-square planar metal centres, showing a topology theoretically predicted but never observed before, and containing uncoordinated ligands as guest molecules.
引用
收藏
页码：1837 / 1838
页数：2
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