Lithium ionic conduction in LiAlO2-based oxides at elevated temperatures

被引：4
作者：
Shimura, T [1 ]
Murahashi, D [1 ]
Iwahara, H [1 ]
Yogo, T [1 ]
机构：
[1] Nagoya Univ, Ctr Integrated Res Sci & Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
来源：
SOLID STATE IONICS: TRENDS IN THE NEW MILLENNIUM, PROCEEDINGS | 2002年
关键词：
D O I：
10.1142/9789812776259_0072
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The ionic conduction behaviors of LiAlO2-based solid solutions, Li1+xAl1-xMgxO2, Li1-x, Al1-x (Si or Ge)(x)O-2 were investigated. In Mg-added samples, the conductivity decreased with increasing x. Si- or Ge-doping enhanced the conductivity. The activation energy increased by Mg-doping, whereas it showed no changes in Si or Ge doped solutions. The influence of the ionic size of doped cations on the conductivity was very small. Electrochemical experiments revealed that the dominant conductive carriers in these oxides were lithium ions.
引用
收藏
页码：613 / 620
页数：8
相关论文
共 14 条
  • [1] Synthesis of lanthanum lithium tantalate powders and thin films by the sol-gel method
    Arakawa, S
    Nitta, H
    Hayashi, S
    [J]. JOURNAL OF CRYSTAL GROWTH, 2001, 231 (1-2) : 290 - 294
  • [2] Garcia Martin S., 1999, SOLID STATE IONICS, V116, P11
  • [3] Influences of carrier concentration and site percolation on lithium ion conductivity in perovskite-type oxides
    Inaguma, Y
    Itoh, M
    [J]. SOLID STATE IONICS, 1996, 86-8 : 257 - 260
  • [4] CANDIDATE COMPOUNDS WITH PEROVSKITE STRUCTURE FOR HIGH LITHIUM IONIC-CONDUCTIVITY
    INAGUMA, Y
    CHEN, LQ
    ITOH, M
    NAKAMURA, T
    [J]. SOLID STATE IONICS, 1994, 70 : 196 - 202
  • [5] Effect of substitution and pressure on lithium ion conductivity in perovskites Ln(1/2)Li(1/2)TiO(3) (Ln=La, Pr, Nd and Sm)
    Inaguma, Y
    Matsui, Y
    Yu, JD
    Shan, YJ
    Nakamura, T
    Itoh, M
    [J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1997, 58 (06) : 843 - 852
  • [6] HIGH IONIC-CONDUCTIVITY IN LITHIUM LANTHANUM TITANATE
    INAGUMA, Y
    CHEN, LQ
    ITOH, M
    NAKAMURA, T
    UCHIDA, T
    IKUTA, H
    WAKIHARA, M
    [J]. SOLID STATE COMMUNICATIONS, 1993, 86 (10) : 689 - 693
  • [7] HIGH LITHIUM ION CONDUCTIVITY IN THE PEROVSKITE-TYPE COMPOUNDS LN1/2LI1/2TIO3 (LN=LA,PR,ND,SM)
    ITOH, M
    INAGUMA, Y
    JUNG, WH
    CHEN, LQ
    NAKAMURA, T
    [J]. SOLID STATE IONICS, 1994, 70 (pt 1) : 203 - 207
  • [8] LITHIUM ION CONDUCTIVITY OF A-SITE DEFICIENT PEROVSKITE SOLID-SOLUTION LA0.67-XLI3XTIO3
    KAWAI, H
    KUWANO, J
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (07) : L78 - L79
  • [9] Ionic conduction of lithium for perovskite type compounds, (Li0.05La0.317)1-xSr0.5xNbO3, (Li0.1La0.3)1-xSr0.5xNbO3 and (Li0.25La0.25)1-xM0.5xNbO3 (M=Ca and Sr)
    Kawakami, Y
    Fukuda, M
    Ikuta, H
    Wakihara, M
    [J]. SOLID STATE IONICS, 1998, 110 (3-4) : 187 - 192
  • [10] Crystal structure and lithium ion conductivity of A-site deficient perovskites La1/3-xLi3xTaO3
    Mizumoto, K
    Hayashi, S
    [J]. JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 1997, 105 (08) : 713 - 715
12