Cu(I)-Catalyzed Carboxylative Coupling of Terminal Alkynes, Allylic Chlorides, and CO2

被引：135

作者：

Zhang, Wen-Zhen ^{[1
]}

Li, Wen-Jie ^{[1
]}

Zhang, Xiao ^{[1
]}

Zhou, Hui ^{[1
]}

Lu, Xiao-Bing ^{[1
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 21期

基金：

中国国家自然科学基金;

关键词：

N-HETEROCYCLIC CARBENES; CARBON-DIOXIDE; CATALYZED CARBOXYLATION; STEREOSELECTIVE-SYNTHESIS; ALKENYLBORONIC ESTERS; COPPER(I); 2-ALKYNOATES; CYCLIZATION; COMPLEXES; CHEMISTRY;

D O I：

10.1021/ol102172v

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A highly selective synthesis of a variety of functionalized allylic 2-alkynoates was realized via the carboxylative coupling of terminal alkynes, allylic chlorides, and CO2 catalyzed by the N-heterocyclic carbene copper(I) complex (IPr)CuCl. The catalyst can be easily recovered without any loss in activity and product selectivity.

引用

页码：4748 / 4751

页数：4

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