Structure of the Microemulsion of Polyglycerol Polyricinoleate Encapsulating Vitamin E

被引:8
作者
Matsuoka, Junji [1 ]
Kusano, Takumi [1 ]
Kasama, Yuuki [2 ]
Tominaga, Etsuko [2 ]
Kobayashi, Junya [2 ]
Fujii, Wataru [2 ]
Iwase, Hiroki [3 ]
Shibayama, Mitsuhiro [1 ]
Nanbu, Hironobu [2 ]
机构
[1] Univ Tokyo, Inst Solid State Phys, 5-1-5 Kashiwanoha, Kashiwa, Chiba 2778581, Japan
[2] Taiyo Kagaku Co Ltd, 1-3 Takara Machi, Yokaichi, Mie 5100844, Japan
[3] Neutron Sci & Technol Ctr, CROSS, 162-1 Tokai, Ibaraki 3191106, Japan
关键词
microemulsion; polyglycerol polyricinoleate; rheology; small angle X-ray scattering; vitamin E;
D O I
10.5650/jos.ess17125
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The structures of micelles and microemulsions consisting of polyglycerol polyricinoleate (PGPR) were investigated by small-angle X-ray scattering (SAXS) and rheological measurements. The SAXS results show that amphiphilic PGPR molecules form stable micelles in glycerol. When vitamin E is added to the PGPR micelles, it is encapsulated in the micelles and forms an emulsion. These micelles are stable towards mechanical shearing up to a shear rate of 1000 s(-1), with shear thinning occurring in the emulsion above 100 s(-1), indicating that the emulsion may undergo break up by shearing, but recovers the structure by releasing shear strain.
引用
收藏
页码:1285 / 1291
页数:7
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