Fabrication of ZnO Thin Films by Sol-Gel Spin Coating and Their UV and White-Light Emission Properties

被引:17
作者
Kumar, Mirgender [1 ]
Dubey, Sarvesh [2 ]
Rajendar, Vanga [1 ]
Park, Si-Hyun [1 ]
机构
[1] Yeungnam Univ, Dept Elect Engn, Gyongsan 38541, South Korea
[2] Shri Ramswaroop Mem Univ, Fac Elect & Commun Engn, Deva Rd, Lucknow, Uttar Pradesh, India
关键词
ZnO thin films; sol-gel method; white-light emission; annealing process; PHOTOLUMINESCENCE; CATHODOLUMINESCENCE; DEPOSITION; MECHANISM;
D O I
10.1007/s11664-017-5565-y
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
ZnO thin films have been fabricated by the sol-gel spin-coating technique and annealed under different conditions, and their ultraviolet (UV) and white-light emission properties investigated. Different ambient conditions including oxygen, nitrogen, zinc-rich nitrogen, and vacuum were used to tune the main properties of the ZnO thin films. The resistivity varied from the conductive to semi-insulating regime, and the luminescence emission from fairly intense UV to polychromatic. The emission intensity was also found to be a function of the annealing conditions. Possible routes to compensate the loss of emission characteristics are discussed. X-ray photoelectron spectroscopy (XPS) analysis was carried out to detect the chemical states of the zinc/oxygen species. The changes in the electrical and emission properties are explained based on annihilation/formation of inherent donor/acceptor-type defects. Such ZnO thin films could have potential applications in solid-state lighting.
引用
收藏
页码:6029 / 6037
页数:9
相关论文
共 39 条
[1]   Effect of sol stabilizer on the structure and electronic properties of solution-processed ZnO thin films [J].
Adl, Ahmad Hossein ;
Kar, Piyush ;
Farsinezhad, Samira ;
Sharma, Himani ;
Shankar, Karthik .
RSC ADVANCES, 2015, 5 (106) :87007-87018
[2]   Zn interstitials and O vacancies responsible for n-type ZnO: what do the emission spectra reveal? [J].
Bandopadhyay, K. ;
Mitra, J. .
RSC ADVANCES, 2015, 5 (30) :23540-23547
[3]   SURFACE EFFECTS ON LOW-ENERGY CATHODOLUMINESCENCE OF ZINC-OXIDE [J].
BYLANDER, EG .
JOURNAL OF APPLIED PHYSICS, 1978, 49 (03) :1188-1195
[4]   Dependence of solution molarity on structural, optical and electrical properties of spin coated ZnO thin films [J].
Chaitra, U. ;
Kekuda, Dhananjaya ;
Rao, K. Mohan .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2016, 27 (07) :7614-7621
[5]  
Chebil W, 2015, INDIAN J PURE AP PHY, V53, P521
[6]   Origin of green luminescence in hydrothermally grown ZnO single crystals [J].
Cizek, J. ;
Valenta, J. ;
Hruska, P. ;
Melikhova, O. ;
Prochazka, I. ;
Novotny, M. ;
Bulir, J. .
APPLIED PHYSICS LETTERS, 2015, 106 (25)
[7]   Photoluminescence and electron paramagnetic resonance of ZnO tetrapod structure [J].
Djurisic, AB ;
Choy, WCH ;
Roy, VAL ;
Leung, YH ;
Kwong, CY ;
Cheah, KW ;
Rao, TKG ;
Chan, WK ;
Lui, HT ;
Surya, C .
ADVANCED FUNCTIONAL MATERIALS, 2004, 14 (09) :856-864
[8]   Transparent conductive ZnO layers on polymer substrates: Thin film deposition and application in organic solar cells [J].
Dosmailov, M. ;
Leonat, L. N. ;
Patek, J. ;
Roth, D. ;
Bauer, P. ;
Scharber, M. C. ;
Sariciftci, N. S. ;
Pedarnig, J. D. .
THIN SOLID FILMS, 2015, 591 :97-104
[9]   The ultraviolet emission mechanism of ZnO thin film fabricated by sol-gel technology [J].
Hsieh, P. T. ;
Chen, Y. C. ;
Kao, K. S. ;
Lee, M. S. ;
Cheng, C. C. .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2007, 27 (13-15) :3815-3818
[10]   High-resistivity GaN buffer templates and their optimization for GaN-based HFETs [J].
Hubbard, SM ;
Zhao, G ;
Pavlidis, D ;
Sutton, W ;
Cho, E .
JOURNAL OF CRYSTAL GROWTH, 2005, 284 (3-4) :297-305