Reactions and applications of titanium imido complexes

被引：258

作者：

Hazari, N ^{[1
]}

Mountford, P ^{[1
]}

机构：

[1] Univ Oxford, Chem Res Lab, Oxford OX1 3TA, England

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2005年 / 38卷 / 11期

关键词：

D O I：

10.1021/ar030244z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This Account highlights aspects of the reactions and applications of titanium imido complexes. Over the past decade in particular, the Ti=NR linkage has been shown to couple stoichiometrically with a variety of unsaturated substrates including CO2, carbodlimides, isocyanates, isocyanides, acetonitrile, phosphaalkynes, alkynes, alkenes, and allenes. Especially recently, there has been much interest in using titanium imides as catalysts for hydroamination and olefin polymerization. The advances in these areas are also reviewed.

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页码：839 / 849

页数：11

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