Insight into metal-enhanced oxidation using barium on 4H-SiC surfaces

被引:13
作者
Chanthaphan, Atthawut [1 ]
Katsu, Yoshihito [1 ]
Hosoi, Takuji [1 ]
Shimura, Takayoshi [1 ]
Watanabe, Heiji [1 ]
机构
[1] Osaka Univ, Grad Sch Engn, Suita, Osaka 5650871, Japan
基金
日本学术振兴会;
关键词
ORIENTATION DEPENDENCE; THERMAL-OXIDATION; SI(111) SURFACES; SI(100) SURFACE; SILICON-CARBIDE; ALKALI-METALS; INTERFACE; DENSITY; OXIDE;
D O I
10.7567/JJAP.55.120303
中图分类号
O59 [应用物理学];
学科分类号
摘要
Metal-enhanced oxidation (MEO) using ultrathin Ba layers on 4H-SiC surfaces was investigated by physical and electrical characterizations. We found that while comparable oxidation rates were enhanced for Si-and C-face surfaces even at a low temperature, significant surface and interface roughness were induced by initial MEO termed the incubation period. Depth profiling revealed that although most Ba atoms aggregated on the oxide surface, a tiny amount (similar to 10(14)cm(-2)) remaining at the oxide interface was responsible for the following stable MEO reaction and the reduced interface state density with the drawbacks of degraded leakage current and breakdown characteristics of SiC-MOS devices. (C) 2016 The Japan Society of Applied Physics
引用
收藏
页数:4
相关论文
共 29 条
[1]   First-principles investigations for oxidation reaction processes at 4H-SiC/SiO2 interface and its orientation dependence [J].
Akiyama, Toru ;
Ito, Ayako ;
Nakamura, Kohji ;
Ito, Tomonori ;
Kageshima, Hiroyuki ;
Uematsu, Masashi ;
Shiraishi, Kenji .
SURFACE SCIENCE, 2015, 641 :174-179
[2]   A strong reduction in the density of near-interface traps at the SiO2/4H-SiC interface by sodium enhanced oxidation [J].
Allerstam, F. ;
Olafsson, H. O. ;
Gudjonsson, G. ;
Dochev, D. ;
Sveinbjornsson, E. O. ;
Rodle, T. ;
Jos, R. .
JOURNAL OF APPLIED PHYSICS, 2007, 101 (12)
[3]   THE DIELECTRIC CONSTANT OF BARIUM OXIDE [J].
BEVER, RS ;
SPROULL, RL .
PHYSICAL REVIEW, 1951, 83 (04) :801-805
[4]   Study of SiO2/4H-SiC interface nitridation by post-oxidation annealing in pure nitrogen gas [J].
Chanthaphan, Atthawut ;
Hosoi, Takuji ;
Shimura, Takayoshi ;
Watanabe, Heiji .
AIP ADVANCES, 2015, 5 (09)
[5]   Investigation of unusual mobile ion effects in thermally grown SiO2 on 4H-SiC(0001) at high temperatures [J].
Chanthaphan, Atthawut ;
Hosoi, Takuji ;
Mitani, Shuhei ;
Nakano, Yuki ;
Nakamura, Takashi ;
Shimura, Takayoshi ;
Watanabe, Heiji .
APPLIED PHYSICS LETTERS, 2012, 100 (25)
[6]   Doping Dependence of Thermal Oxidation on n-Type 4H-SiC [J].
Daas, B. K. ;
Islam, M. M. ;
Chowdhury, Iftekhar A. ;
Zhao, Feng ;
Sudarshan, T. S. ;
Chandrashekhar, M. V. S. .
IEEE TRANSACTIONS ON ELECTRON DEVICES, 2011, 58 (01) :115-121
[7]   GENERAL RELATIONSHIP FOR THERMAL OXIDATION OF SILICON [J].
DEAL, BE ;
GROVE, AS .
JOURNAL OF APPLIED PHYSICS, 1965, 36 (12) :3770-&
[8]   Structure and chemistry of passivated SiC/SiO2 interfaces [J].
Dycus, J. Houston ;
Xu, Weizong ;
Lichtenwalner, Daniel J. ;
Hull, Brett ;
Palmour, John W. ;
LeBeau, James M. .
APPLIED PHYSICS LETTERS, 2016, 108 (20)
[9]   THE EFFECT OF SR AND BI ON THE SI(100) SURFACE OXIDATION - AUGER-ELECTRON SPECTROSCOPY, LOW-ENERGY ELECTRON-DIFFRACTION, AND X-RAY PHOTOELECTRON-SPECTROSCOPY STUDY [J].
FAN, WC ;
MESARWI, A ;
IGNATIEV, A .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1990, 8 (06) :4017-4020
[10]   EFFECT OF BA ON THE OXIDATION OF THE SI(100) SURFACE [J].
FAN, WC ;
IGNATIEV, A .
PHYSICAL REVIEW B, 1991, 44 (07) :3110-3114