Supramolecular isomerism of a metallocyclic dipyridyldiamide ligand metal halide system generating isostructural (Hg, Co and Zn) porous materials

被引：42

作者：

Jones, Christopher D. ^{[1
]}

Tan, Jin Chong ^{[2
]}

Lloyd, Gareth O. ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[2] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 15期

关键词：

ORGANIC FRAMEWORKS; COORDINATION NETWORKS; THERMAL-PROPERTIES; SINGLE-CRYSTAL; ANION-BINDING; HYDROGEN; POLYMERS; ADSORPTION; PHOTOLUMINESCENCE; POLYMORPHISM;

D O I：

10.1039/c2cc16691g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We show how crystallisation of supramolecular isomers of a dynamic coordination system generates a series of isostructural porous materials. These mercury, cobalt and zinc metallocyclic materials show permanent porosity and exhibit single-crystal-to-single-crystal transformations.

引用

页码：2110 / 2112

页数：3

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