The maximum hardness principle and the composition of Zn(II) and Cd(II) tetrafluoroborate complexes with nitrogen-containing organic bases

被引：0
作者：
Chebotarev, AN [1 ]
Shestakova, MV [1 ]
Kuz'min, VE [1 ]
Artemenko, AG [1 ]
机构：
[1] Mechnikov Univ, UA-270014 Odessa, Ukraine
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2005年 / 31卷 / 09期
关键词：
D O I：
10.1007/s11173-005-0145-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The hardness/softness parameters of the central complexing ion, the donor nitrogen atom of the ligand, and the coordination bond were calculated for zinc and cadmium tetrafluoroborate complexes with nitrogen-containing organic bases of various composition (both experimentally determined and hypothetical). On the basis of the quantitative estimate of the hard/soft characteristics of the whole series of the coordination compounds considered, it was found that the hardest parameters are inherent in the complexes isolated in a pure state by a preparative method.
引用
收藏
页码：619 / 622
页数：4
相关论文
共 50 条
[41]   Spectroscopy and photophysics of binuclear ruthenium(II) complexes with nitrogen-containing heterocyclic bridging ligands [J].
S. V. Litke ;
T. V. Udalova ;
G. N. Lyalin ;
A. Yu. Ershov .
Optics and Spectroscopy, 2005, 99 :905-911
[42]   COMPLEXES OF BIS(HEXAFLUOROACETYLACETONATO)COPPER(II) WITH SOME NITROGEN-CONTAINING CHELATES AND ETHYLENE GLYCOL [J].
FENTON, DE ;
NYHOLM, RS ;
TRUTER, MR .
JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (10) :1577-&
[43]   Spectroscopy and photophysics of binuclear ruthenium(II) complexes with nitrogen-containing heterocyclic bridging ligands [J].
Litke, SV ;
Udalova, TV ;
Lyalin, GN ;
Ershov, AY .
OPTICS AND SPECTROSCOPY, 2005, 99 (06) :905-911
[44]   TRANSITION-METAL COMPLEXES WITH NITROGEN-CONTAINING LIGANDS .1. COPPER(II) - BENZOTRIAZOLE COMPLEXES [J].
KARWECKA, Z ;
PAJDOWSKI, L .
ROCZNIKI CHEMII, 1976, 50 (7-8) :1251-1256
[45]   Synthesis, spectral characterization and biological activity of benzofuran Schiff bases with Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) complexes [J].
Shivakumar, K. ;
Shashidhar, T. ;
Reddy, P. Vithal ;
Halli, M. B. .
JOURNAL OF COORDINATION CHEMISTRY, 2008, 61 (14) :2274-2287
[46]   FE(II), CO(II), NI(II), CU(II), ZN(II), PD(II), CD(II) AND UO2(II) COMPLEXES OF TRIDENTATE SCHIFF-BASES [J].
MEHTA, RK ;
GUPTA, RK .
INDIAN JOURNAL OF CHEMISTRY, 1973, 11 (01) :56-58
[47]   Syntheses and reactions of iron(II) complexes containing diphosphine ligands with pendant nitrogen bases [J].
Jacobsen, George M. ;
Shoemaker, R. K. ;
DuBois, M. Rakowski ;
DuBois, Daniel L. .
ORGANOMETALLICS, 2007, 26 (20) :4964-4971
[48]   DFT study of olefin versus nitrogen bonding in the coordination of nitrogen-containing polar monomers to diimine and salicylaldiminato nickel(II) and palladium(II) complexes. Implications for copolymerization of olefins with nitrogen-containing polar monomers [J].
Deubel, DV ;
Ziegler, T .
ORGANOMETALLICS, 2002, 21 (08) :1603-1611
[49]   PHYSICOCHEMICAL STUDIES ON THE COMPOSITION AND STABILITY-CONSTANTS OF ZN(II), CD(II) AND HG(II) DL-VALINE COMPLEXES [J].
SAXENA, RS ;
SHARMA, GL .
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1982, 59 (05) :635-637
[50]   Heteroligand copper(II) complexes with hydroxyethyleneiminodiacetic acid and bidentate nitrogen-containing ligands: Structures and properties [J].
D. A. Kutolei ;
A. V. Shtemenko .
Russian Journal of Coordination Chemistry, 2013, 39 :857-866
12345