The maximum hardness principle and the composition of Zn(II) and Cd(II) tetrafluoroborate complexes with nitrogen-containing organic bases

被引：0
作者：
Chebotarev, AN [1 ]
Shestakova, MV [1 ]
Kuz'min, VE [1 ]
Artemenko, AG [1 ]
机构：
[1] Mechnikov Univ, UA-270014 Odessa, Ukraine
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2005年 / 31卷 / 09期
关键词：
D O I：
10.1007/s11173-005-0145-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The hardness/softness parameters of the central complexing ion, the donor nitrogen atom of the ligand, and the coordination bond were calculated for zinc and cadmium tetrafluoroborate complexes with nitrogen-containing organic bases of various composition (both experimentally determined and hypothetical). On the basis of the quantitative estimate of the hard/soft characteristics of the whole series of the coordination compounds considered, it was found that the hardest parameters are inherent in the complexes isolated in a pure state by a preparative method.
引用
收藏
页码：619 / 622
页数：4
相关论文
共 50 条
[21]   TERNARY COMPLEXES OF COPPER(II) WITH MIXED ACETYLACETONATE AND NITROGEN-CONTAINING LIGANDS [J].
BAILEY, NA ;
FENTON, DE ;
FRANKLIN, MV ;
HALL, M .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (06) :984-990
[22]   Palladium(II) complexes with polydentate sulfur- and nitrogen-containing ligands [J].
Kolotilov, SV ;
Goreshnik, EA ;
Pavlishchuk, VV ;
Yatsimirskii, KB .
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2000, 45 (06) :868-875
[23]   RATES OF REACTION OF COMPLEXES OF NICKEL(II) WITH NITROGEN-CONTAINING UNIDENTATE LIGANDS [J].
MELSON, GA ;
WILKINS, RG .
JOURNAL OF THE CHEMICAL SOCIETY, 1962, (10) :4208-&
[24]   Sorption of palladium(II) chloride complexes by nitrogen-containing modified shungites [J].
A. M. Akimbaeva .
Russian Journal of Applied Chemistry, 2006, 79 :559-562
[25]   Sorption of palladium(II) chloride complexes by nitrogen-containing modified shungites [J].
Akimbaeva, A.M. .
Russian Journal of Applied Chemistry, 2006, 79 (04) :559-562
[26]   Tin(II) sulfatofluoride polymeric compounds with nitrogen-containing organic cations [J].
Gorbunova, YE ;
Kokunov, YV ;
Detkov, DG ;
Mikhailov, YN .
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2003, 48 (10) :1487-1492
[27]   Synthesis and structural studies of bidentate Schiff bases and their complexes with Cu(II), Ni(II), Co(II), Cd(II) and Zn(II) [J].
Poyraz, Mehmet ;
Yenikaya, Cengiz ;
Colak, Alper Tolga .
ASIAN JOURNAL OF CHEMISTRY, 2008, 20 (05) :3515-3524
[28]   Reduction of α,β-unsaturated carbonyl compounds by palladium(II) and nickel(II) complexes having nitrogen-containing ligands [J].
Jana, Partha R. ;
Sarma, Rupam ;
Baruah, Jubaraj B. .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 289 (1-2) :57-60
[29]   Nickel(II) complexes with nitrogen-containing derivatives of the closo-decaborate anion [J].
Kubasov, A. S. ;
Matveev, E. Yu. ;
Retivov, V. M. ;
Akimov, S. S. ;
Razgonyaeva, G. A. ;
Polyakova, I. N. ;
Votinova, N. A. ;
Zhizhin, K. Yu. ;
Kuznetsov, N. T. .
RUSSIAN CHEMICAL BULLETIN, 2014, 63 (01) :187-193
[30]   Nickel(II) complexes with nitrogen-containing derivatives of the closo-decaborate anion [J].
A. S. Kubasov ;
E. Yu. Matveev ;
V. M. Retivov ;
S. S. Akimov ;
G. A. Razgonyaeva ;
I. N. Polyakova ;
N. A. Votinova ;
K. Yu. Zhizhin ;
N. T. Kuznetsov .
Russian Chemical Bulletin, 2014, 63 :187-193
12345