The maximum hardness principle and the composition of Zn(II) and Cd(II) tetrafluoroborate complexes with nitrogen-containing organic bases

被引：0

作者：

Chebotarev, AN ^{[1
]}

Shestakova, MV ^{[1
]}

Kuz'min, VE ^{[1
]}

Artemenko, AG ^{[1
]}

机构：

[1] Mechnikov Univ, UA-270014 Odessa, Ukraine

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2005年 / 31卷 / 09期

关键词：

D O I：

10.1007/s11173-005-0145-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hardness/softness parameters of the central complexing ion, the donor nitrogen atom of the ligand, and the coordination bond were calculated for zinc and cadmium tetrafluoroborate complexes with nitrogen-containing organic bases of various composition (both experimentally determined and hypothetical). On the basis of the quantitative estimate of the hard/soft characteristics of the whole series of the coordination compounds considered, it was found that the hardest parameters are inherent in the complexes isolated in a pure state by a preparative method.

引用

页码：619 / 622

页数：4

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