Energetic characteristics of barium cerates doped by yttrium, gadolinium and luthetium oxides

被引：6
作者：
Matskevich, N. I. [1 ,2 ]
Wolf, Th. [1 ]
Matskevich, M. Yu. [2 ,3 ]
机构：
[1] Karlsruhe Inst Technol, Inst Solid State Phys, D-76334 Karlsruhe, Germany
[2] RAS, Nikolaev Inst Inorgan Chem SB, Novosibirsk 630090, Russia
[3] Novosibirsk State Univ, Novosibirsk 630090, Russia
来源：
JOURNAL OF CHEMICAL THERMODYNAMICS | 2018年 / 118卷
关键词：
Barium cerate; Formation enthalpy; Stabilization energy; Lattice energy; THERMODYNAMIC STABILITY; PROTON CONDUCTOR; ELECTROLYTES; ENTHALPIES; BACEO3;
D O I：
10.1016/j.jct.2017.11.010
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
For the first time solution enthalpies of BaCe0.8Y0.1Gd0.1O2.9, BaCe0.8Y0.1Lu0.1O2.9 and mixtures of BaCl2 + 0.8CeCl(3) + 0.1YCl(3) + 0.1GdCl(3), BaCl2 + 0.8CeCl(3) + 0.1YCl(3) + 0.1LuCl(3) in 1 mol dm(-3) HCl with 0.1 mol dm(-3) KI have been measured. On the basis of experimental data obtained and literature data the standard molar enthalpies of formation and stabilization energies were calculated. Using Born-Haber cycle the lattice energies were calculated. It was established that lattice energy was increased from BaCe0.8Y0.1Gd0.1O2.9 to BaCe0.8Y0.1Lu0.1O2.9. It correlates with decreasing of ion radius of rare earth element from gadolinium to lutetium. Increasing of lattice energy with decreasing of ion radius of rare earth element was explained with modified formula of Kapustinskii. (C) 2017 Elsevier Ltd.
引用
收藏
页码：188 / 192
页数：5
相关论文
共 24 条
  • [11] Synthesis and thermodynamic stability of new phase BaCe0.6Y0.3In0.1O2.8
    Matskevich, N. I.
    Wolf, Th.
    Matskevich, M. Yu.
    Bryzgalova, A. N.
    Chupakhina, T. I.
    Vyazovkin, I. V.
    [J]. THERMOCHIMICA ACTA, 2014, 579 : 22 - 26
  • [12] Synthesis and thermochemistry of new phase BaCe0.7Nd0.2In0.1O2.85
    Matskevich, Nata I.
    Matskevich, Mariya Yu
    Wolf, Thomas
    Bryzgalova, Anna N.
    Chupakhina, Tatyana I.
    Anyfrieva, Olga I.
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 577 : 148 - 151
  • [13] Calorimetric investigation of new Bi12.5Dy1.5ReO24.5 phase
    Matskevich, Nata I.
    Wolf, Thomas
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2012, 538 : 45 - 47
  • [14] The enthalpies of formation of BaCe1-xRExO3-δ (RE = Eu, Tb, Gd)
    Matskevich, Nata I.
    Wolf, Thomas A.
    [J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 2010, 42 (02) : 225 - 228
  • [15] Preparation, Stability and Thermodynamic Properties of Nd- and Lu-Doped BaCeO3 Proton-Conducting Ceramics
    Matskevich, Nata I.
    Wolf, Thomas
    Matskevich, Mariya Yu.
    Chupakhina, Tatiana I.
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (11) : 1477 - 1482
  • [16] Prediction of Partition Coefficients of Organic Compounds in Ionic Liquids Using a Temperature-Dependent Linear Solvation Energy Relationship with Parameters Calculated through a Group Contribution Method
    Mutelet, Fabrice
    Ortega-Villa, Virginia
    Moise, Jean-Charles
    Jaubert, Jean-Noel
    Acree, William E., Jr.
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2011, 56 (09) : 3598 - 3606
  • [17] Thermodynamics of solid phases containing rare earth oxides
    Navrotsky, Alexandra
    Lee, Wingyee
    Mielewczyk-Gryn, Aleksandra
    Ushakov, Sergey V.
    Anderko, Andre
    Wu, Haohan
    Riman, Richard E.
    [J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 2015, 88 : 126 - 141
  • [18] Qiu LG, 2014, CHINESE J INORG CHEM, V30, P2503
  • [19] Thermodynamic stability of lead-free alkali niobate and tantalate perovskites
    Sahu, Sulata K.
    Zlotnik, Sebastian
    Navrotsky, Alexandra
    Vilarinho, Paula M.
    [J]. JOURNAL OF MATERIALS CHEMISTRY C, 2015, 3 (29) : 7691 - 7698
  • [20] Samarium and Yttrium Codoped BaCeO3 Proton Conductor with Improved Sinterability and Higher Electrical Conductivity
    Shi, Zhen
    Sun, Wenping
    Wang, Zhongtao
    Qian, Jing
    Liu, Wei
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (07) : 5175 - 5182
123