Living radical polymerization of acrylates and acrylamides mediated by a versatile cobalt porphyrin complex

被引：24

作者：

Zhao, Yaguang ^{[3
]}

Dong, Huilong ^{[1
,2
]}

Li, Youyong ^{[1
,2
]}

Fu, Xuefeng ^{[3
]}

机构：

[1] Soochow Univ, Inst Funct Nano & Soft Mat FUNSOM, Suzhou 215123, Jiangsu, Peoples R China

[2] Soochow Univ, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Suzhou 215123, Jiangsu, Peoples R China

[3] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 29期

关键词：

VINYL-ACETATE; POLY(ACRYLIC ACID); NITROXIDE; HYDROGELS; WATER; METHACRYLATES; COPOLYMERS; UNIVERSAL; CATALYSTS; STYRENE;

D O I：

10.1039/c2cc00114d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Living radical polymerization (LRP) of organic and water soluble acrylates and acrylamides was mediated by a versatile cobalt porphyrin complex (TMP-OH)Co. The capability of this cobalt complex to mediate LRP in both polar and non-polar media permits the direct synthesis of useful and previously difficult to prepare functional block copolymers.

引用

页码：3506 / 3508

页数：3

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