A 2,2′-azobenzene-substituted calix[4]-arene-crown-6

被引：4
|
作者：
Thuéry, P
Nierlich, M
Saadioui, M
Asfari, Z
Vicens, J
机构：
[1] CEA Saclay, SCM, CNRS, URA 331, F-91191 Gif Sur Yvette, France
[2] CNRS, URA 405, Lab Chim Interact Mol Specif, F-67008 Strasbourg, France
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷
关键词：
D O I：
10.1107/S0108270198013882
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The calix[4]arene macrocycle, 25,27-dihydroxy-26,28(O,O' -azobenzene)calix[4]arene-crown-6 [which crystallizes as an N,N-dimethylformamide solvate (C48H46N2O8. C3H7NO)], in the cone conformation, has two opposite phenolic rings bridged by an -(O-CH2-CH2)(2)O-C6H4-N=N-C6H4-(O-CH2-CH2)(2)O-unit. The two other phenolic O atoms are unsubstituted. The azobenzene geometry is the more stable trans one. This structure is compared to other previously reported structures, involving differently bonded azobenzene moieties.
引用
收藏
页码：443 / 445
页数：3
相关论文
共 50 条
  • [1] Partial cone calix[4]arene-crown-6 ethers.
    Das, G
    Sachleben, RA
    Descazeaud, T
    Bryan, JC
    Moyer, BA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 213 : 16 - IEC
  • [2] Synthesis of calix[4]arene-crown-6 with alkoxysilyl-containing substituents
    E. A. Alekseeva
    S. S. Basok
    A. V. Mazepa
    A. I. Gren’
    Russian Journal of Organic Chemistry, 2008, 44 : 348 - 352
  • [3] Extraction of cesium by calix[4]arene-crown-6: From synthesis to process
    Dozol, J.-F.
    Lamare, V.
    Simon, N.
    Ungaro, R.
    Casnati, A.
    ACS Symposium Series, 2000, 757 : 12 - 25
  • [4] Synthesis of calix[4]arene-crown-6 with alkoxysilyl-containing substituents
    Alekseeva, E. A.
    Basok, S. S.
    Mazepa, A. V.
    Gren, A. I.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 44 (03) : 348 - 352
  • [5] Laser-induced dealkylation of calix[4]arene-crown-6 ethers
    Jankowski, Christopher K.
    Hocquelet, Celine
    Arseneau, Sebastien
    Moulin, Christophe
    Mauclaire, Laurent
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2006, 184 (1-2) : 216 - 220
  • [6] Extraction of cesium by a calix[4]arene-crown-6 ether bearing a pendant amine group
    Harmon, Ben W.
    Ensor, Dale D.
    Delmau, Laetitia H.
    Moyer, Bruce A.
    SOLVENT EXTRACTION AND ION EXCHANGE, 2007, 25 (03) : 373 - 388
  • [7] A new ion selective electrode for cesium (I) based on calix[4]arene-crown-6 compounds
    Ramanjaneyulu, P. S.
    Kumar, Abha Naveen
    Sayi, Y. S.
    Ramakumar, K. L.
    Nayak, S. K.
    Chattopadhyay, S.
    JOURNAL OF HAZARDOUS MATERIALS, 2012, 205 : 81 - 88
  • [8] Lower Rim Substituted tert-Butyl calix[4]arene (part VII): Ionophoric Properties of Calix[4]arene-crown-6 Derivatives in Plasticized PVC-Membrane Electrodes and in Solution
    Maria Bocheńska
    Anna Zielińska
    Radosław Pomećko
    Véronique Hubscher-Bruder
    Françoise Arnaud-Neu
    Journal of inclusion phenomena and macrocyclic chemistry, 2005, 52 : 129 - 134
  • [9] Lower rim substituted tert-butyl calix[4]arene (part VII):: Ionophoric properties of calix[4]arene-crown-6 derivatives in plasticized PVC-membrane electrodes and in solution
    Bochenska, M
    Zielinska, A
    Pomecko, R
    Hubscher-Bruder, V
    Arnaud-Neu, F
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2005, 52 (1-2) : 129 - 134
  • [10] Synthesis and characterization of immunogens based on calix[4]arene-crown-6 for the generation of antibodies directed towards cesium ions
    Safi, Samir
    Asfari, Zouhair
    Ehret-Sabatier, Laurence
    Leroy, Maurice
    Hagege, Agnes
    BIOCONJUGATE CHEMISTRY, 2006, 17 (05) : 1346 - 1350
12345