Enzyme-catalyzed hydrolysis of unsaturated polyester networks .1. Study of the hydrolysis of a precursor: Poly(1,2-propanediyl fumarate)

被引：0

作者：

Valiente, N ^{[1
]}

Lalot, T ^{[1
]}

Brigodiot, M ^{[1
]}

Marechal, E ^{[1
]}

机构：

[1] UNIV PARIS 06, CNRS URA 24, LAB SYNTH MACROMOL, F-75252 PARIS 05, FRANCE

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1997年 / 35卷 / 01期

关键词：

enzyme; lipase; hydrolytic degradation; unsaturated polyester; poly(1,2-propanediyl fumarate);

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Hydrolytic degradation of poly(1,2-propanediyl fumarate) was carried out in mild experimental conditions using Chromobacterium viscosum lipase as catalyst. The influence of pH, temperature, enzyme concentration, and enzyme inactivation on the initial hydrolysis rate has been analyzed. Enzymatic and chemical processes were compared. This study is an introduction to the enzyme-catalyzed hydrolysis of networks based on unsaturated polyesters. (C) 1997 John Wiley & Sons, Inc.

引用

页码：27 / 34

页数：8

共 17 条

[1] Enzyme-catalyzed hydrolysis of unsaturated polyester networks .2. Enzyme-catalyzed hydrolysis of polyester networks prepared from poly(1,2-propanediyl fumarate)
Valiente, N
Lalot, T
Brigodiot, M
Marechal, E
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1997, 35 (01) : 35 - 40
[2] ENZYME-CATALYZED SYNTHESES OF POLY(1,6-HEXANEDIYL MALEATE) AND POLY(1,6-HEXANEDIYL FUMARATE) IN ORGANIC MEDIUM
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[3] RESOLUTION OF (1,1'-BINAPHTHALENE)-2,2'-DITHIOL BY ENZYME-CATALYZED HYDROLYSIS OF A RACEMIC DIACYL DERIVATIVE
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NUBER, B
TETRAHEDRON, 1994, 50 (24) : 7109 - 7114
[4] Enzyme-mediated enantioselective hydrolysis of 1,2-diol monotosylate derivatives bearing an unsaturated substituent
Matsumoto, K.
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[5] Enzyme-catalyzed enantioselective hydrolysis of diacetylated (±)-1-(2′,3′-dideoxy-3′-fluoroapio-β-furanosyl) cytosine
Song, M
Ahn, Y
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2001, 22 (04) : 427 - 428
[6] EVIDENCE FOR A NEW ENZYME-CATALYZED REACTION OTHER THAN BETA-LACTAM HYDROLYSIS IN TURNOVER OF A PENEM BY THE TEM-1 BETA-LACTAMASE
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MOBASHERY, S
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (12) : 4962 - 4965
[7] Enzyme-catalyzed synthesis of poly(1,6-hexanediyl maleate-co-fumarate) in organic medium. Study of macrolactone formation in relation to the composition of the initial monomer mixture
Mezoul, G
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MACROMOLECULAR CHEMISTRY AND PHYSICS, 1996, 197 (11) : 3581 - 3592
[8] STRUCTURE AND REACTIVITY OF ALPHA,BETA-UNSATURATED ETHERS .13. CATIONIC COPOLYMERIZATION AND ACID-CATALYZED HYDROLYSIS OF 1,2-DIALKOXYETHYLENES
OKUYAMA, T
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JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1971, 9 (03): : 629 - &
[9] Lipase-catalyzed kinetic resolution of threo-configured 1,2-diols:: a comparative study of transesterification versus hydrolysis
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Díaz, MT
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TETRAHEDRON-ASYMMETRY, 1998, 9 (04) : 589 - 598
[10] KINETIC STUDY OF PHOSPHOLIPASE A2 (CROTALUS-ADAMANTEUS) CATALYZED-HYDROLYSIS OF 1,2-DIBUTYRL-SN-GLYCERO-3-PHOSPHORYLCHOLINE
WELLS, MA
BIOCHEMISTRY, 1972, 11 (06) : 1030 - +

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