Heat transfer characterization of metallic foams

被引:142
作者
Giani, L [1 ]
Groppi, G [1 ]
Tronconi, E [1 ]
机构
[1] Politecn Milan, NEMAS, Ctr Eccellenza Ingn Mat & Superfici Nanostrutt, Dipartimento Chim Mat Ingn Chim G Natta, I-20133 Milan, Italy
关键词
D O I
10.1021/ie050598p
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Gas-solid heat transfer coefficients were determined in open-celled metal foams as part of a study aimed at evaluating the application of metal foams as catalyst supports in gas-solid catalytic processes with short contact times and high reaction rates, typically controlled by diffusional mass transport. Examples of such processes are found in the field of environmental catalysis, including, for example, catalytic combustion, selective catalytic reduction of NOx by NH3 (SCR-DeNOx), automotive exhaust gas after treatment, and also in the catalytic partial oxidation of hydrocarbons for syngas or H-2 generation processes. In this work, foam samples made of FeCrAlloy and Cu with nominal porosities of 10 and 20 pores per inch (ppi) were characterized by performing non-steady-state cooling measurements. Convective gas-solid heat transfer coefficients were determined by applying a one-dimensional, heterogeneous model of the cooling structure. The correlation Nu = 1.2Re(0.43)Pr(1/3) well described the dependence of the dimensionless heat transfer coefficients on Re and Pr numbers for all the tests made in a range of flow superficial velocities from 1.2 to 5.7 m/s, independently from the foam cell size (20 < Re < 240). Such a correlation was derived assuming a prismatic idealization of the unit cell and selecting the equivalent strut diameter as the characteristic size of the foams. This expression satisfies the Colburn analogy with the correlation for mass transfer coefficients derived in a previous investigation and resembles semitheoretical. literature correlations for heat transfer in flow across banks of tubes at low Reynolds numbers.
引用
收藏
页码:9078 / 9085
页数:8
相关论文
共 19 条
[1]   Manufacture, characterisation and application of cellular metals and metal foams [J].
Banhart, J .
PROGRESS IN MATERIALS SCIENCE, 2001, 46 (06) :559-U3
[2]   On the effective thermal conductivity of a three-dimensionally structured fluid-saturated metal foam [J].
Boomsma, K ;
Poulikakos, D .
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2001, 44 (04) :827-836
[3]   Heat transfer characterization of support structures for catalytic combustion [J].
Brautsch, A ;
Griffin, T ;
Schlegel, A .
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2002, 45 (15) :3223-3231
[4]   POWERFUL METHOD FOR HOUGEN-WATSON MODEL PARAMETER ESTIMATION WITH INTEGRAL CONVERSION DATA [J].
FERRARIS, GB ;
DONATI, G .
CHEMICAL ENGINEERING SCIENCE, 1974, 29 (06) :1504-1509
[5]   Effective and coupled thermal conductivities of isotropic open-cellular foams [J].
Fourie, JG ;
Du Plessis, JP .
AICHE JOURNAL, 2004, 50 (03) :547-556
[6]  
Fourie JG, 2002, CHEM ENG SCI, V57, P2781
[7]   Mass-transfer characterization of metallic foams as supports for structured catalysts [J].
Giani, L ;
Groppi, G ;
Tronconi, E .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2005, 44 (14) :4993-5002
[8]   Washcoating method for Pd/-γ-Al2O3 deposition on metallic foams [J].
Giani, L ;
Cristiani, C ;
Groppi, G ;
Tronconi, E .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 62 (1-2) :121-131
[9]  
GIBSON LJ, 1988, CELLULAR SOLIDS
[10]  
Hindmarsh A. C, 1983, IMACS T SCI COMPUTAT, V1, P55