The neutral envelopes around age and post-AGB objects

The circumstellar gas/dust envelopes of stars on and beyond the asymptotic giant branch harbor an impressive number of different molecular species and their isotopic variants. Some of these molecules are of photospheric origin, but the majority have been produced through various chemical processes in the envelope. This chemistry depends primarily on the chemical composition of the gas (i.e., C/O<1 or >1), but the conditions also change as the central star evolves. In this review we present circumstellar molecular abundance and isotope ratio estimates, and discuss how they can be used in the study of the late evolution of stars, which in extreme cases may become heavily obscured.