Novel borate supramolecular frameworks constructed from isolated B4/B5 clusters and 1-D B17-based chains

被引：6
作者：
Wang, Jia-Jia [1 ]
Yang, Guo-Yu [1 ,2 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Beijing Inst Technol, Sch Chem & Chem Engn, MOE Key Lab Cluster Sci, Beijing 102488, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2017年 / 85卷
关键词：
Borate; Hydrogen bond; Solvothermal synthesis; Supramolecular framework; Cluster; FUNDAMENTAL BUILDING-BLOCKS; NONLINEAR-OPTICAL CRYSTAL; UNITS; ULTRAVIOLET; ANION; MINERALS; CHANNELS; BAND; BO3;
D O I：
10.1016/j.inoche.2017.07.004
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three new borates [Cu(1,3-dap)(2)(H2O)(2)][Cu(1,3-dap)(2)(B(OH)(3))2][B4O5(OH)(4)](2) (1, 1,3-dap = 1,3-diaminopropane), [Cu(PY)(4)(H2O)][B5O6(OH)(4)](2)center dot 3PY center dot H2O (2, py = pyridine) and (HDMF)(2) INH(CH3)(3)](4)[NH2(CH3)(2)](2)Mg-2[B17O26(OH)(4)][B17O27(OH)(4)]center dot NH3 (3, DMF = N,N-dimethylformamide) have been synthesized under mild solvothermal conditions and characterized by elemental analysis, IR spectra, diffuse reflectance spectra, thermogravimetric analysis, single -crystal X-ray diffraction and powder X-ray diffraction. I and 2 exhibit 3-D supramolecular hydrogen -bonded architectures constructed from isolated oxoboron clusters [B4O5(OH)(4)](2-) and B5O6(OH)(4)](-), respectively. The structure of 3 features two different 1-D chains built by unprecedented [B17O26(OH)(4)](5-) and [B17O27(OH)(4)](7-) clusters, respectively. And the adjacent chains are alternatively linked by H -bonding to form a 3-D supramolecular framework. (C) 2017 Elsevier B.V. All rights reserved.
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页码：92 / 95
页数：4
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