A pcu-type metal-organic framework based on covalently quadruple cross-linked supramolecular building blocks (SBBs): structure and adsorption properties

被引：36

作者：

Li, Chuanqiang ^{[1
]}

Qiu, Wenge ^{[1
]}

Shi, Wei ^{[2
]}

Song, Haibin ^{[2
]}

Bai, Guangmei ^{[1
]}

He, Hong ^{[1
]}

Li, Jian ^{[1
]}

Zaworotko, Michael J. ^{[3
]}

机构：

[1] Beijing Univ Technol, Dept Chem Sci & Engn, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

[2] Nankai Univ, Coll Chem, Tianjin 300071, Peoples R China

[3] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

来源：

CRYSTENGCOMM | 2012年 / 14卷 / 06期

关键词：

CRYSTAL-STRUCTURE; METHANE STORAGE; GAS-ADSORPTION; CARBON-DIOXIDE; HIGH-CAPACITY; CO2; BINDING; DESIGN; CHEMISTRY; SORPTION; NETWORK;

D O I：

10.1039/c2ce06384k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A flexible ligand with two 1,3-benzenedicarboxylate units has been used to construct a microporous metal-organic framework with pcu topology based on supramolecular building blocks (SBBs). The obtained Cu(II) MOF exhibits a noticeable CO2 adsorption hysteresis and a comparable methane adsorption capacity at room temperature.

引用

页码：1929 / 1932

页数：4

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