Copolymers of 2-(3-mesityl-3-methyleyclobutyl)-2-ketoethyl methacrylate with acrylonitrile and styrene: Synthesis, characterization, and monomer reactivity ratios

被引：5

作者：

Erol, I ^{[1
]}

Ahmedzade, M

机构：

[1] Univ Afyon Kocatepe, Fac Sci & Arts, Dept Chem, Afyon, Turkey

[2] Univ Firat, Fac Sci & Arts, Dept Chem, Elazig, Turkey

来源：

JOURNAL OF POLYMER RESEARCH | 2005年 / 12卷 / 04期

关键词：

copolymers; cyclobutane; ketoethyl methacrylate; monomer reactivity ratios;

D O I：

10.1007/s10965-004-4674-5

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The copolymerization of 2-(3-mesityl-3-methylcyclobutyl)-2-ketoethyl methacrylate monomer with acrylonitrile and styrene were carried out in 1,4-dioxane solution at 60 degrees C using AIBN as an initiator. The copolymers were characterized by Fourier transform infrared, H-1-NMR, and C-13-NMR spectroscopic techniques. Thermal properties of the polymers were also studied by thermogravimetric analysis and differential scanning calorimetry. The copolymer compositions were determined by elemental analysis and H-1-NMR technique. The monomer reactivity ratios were calculated by the application of conventional linearization methods as a result of Fineman-Ross and Kelen-Tudos to less than 1 for both monomers.

引用

页码：247 / 255

页数：9

共 23 条

[1]

AKELAH A, 1990, FUNCTIONALIZED POLYM

[2]

[Anonymous], J MACROMOL SCI A

[3]

ARSHADY R, 1981, MACROMOL CHEM PHYS, V182, P41

[4] NITRILE FUNCTION AS A PROBE OF CIS TRANS STEREOCHEMISTRY - C-13 NMR-STUDIES OF POLY(BICYCLOBUTANE-1-CARBONITRILE) AND RELATED MODEL COMPOUNDS [J].

BARFIELD, M ;

KAO, LF ;

HALL, HK ;

SNOW, LG .

MACROMOLECULES, 1984, 17 (02) :240-248

[5]

BILMEYER FW, 1984, TXB POLYM SCI, P119

[6] EFFECT OF CYCLOBUTANE CARBONITRILE RINGS ON THE GLASS-TRANSITION TEMPERATURE OF VINYL CO-POLYMERS [J].

COLLETTE, JW ;

GALE, DM ;

BELLETETE, MG .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1980, 18 (03) :1071-1078

[7]

Coskun M, 1997, J POLYM SCI POL CHEM, V35, P2123

[8]

COSKUN M, 2000, POLYM DEGRAD STABIL, V78, P49

[9] A CONVENIENT ROUTE TO A NEW BICYCLOBUTANE MONOMER - ISOPROPYL 1-BICYCLOBUTANECARBOXYLATE [J].

DRUJON, X ;

HALL, HK .

POLYMER BULLETIN, 1990, 24 (02) :181-185

[10] Monomer reactivity ratios of the 2-(3-mesityl-3-methylcyclobutyl)-2-hydroxyethyl methacrylate and styrene system from 1H NMR [J].

Erol, I ;

Soykan, C ;

Ahmedzade, M .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (11) :1756-1763

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