Application of Nickel (II) Complex of Dithiocarbamate-Modified Starch for Anionic Dyes Removal from Aqueous Solutions

被引：9

作者：

Cheng, Rumei ^{[1
]}

Xiang, Bo ^{[2
]}

Li, Yijiu ^{[2
]}

机构：

[1] Wenzhou Med Coll, Sch Ophthalmol & Optometry, Inst Adv Mat Nanobio Applicat, Wenzhou, Peoples R China

[2] Tongji Univ, Dept Chem, Shanghai, Peoples R China

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2012年 / 123卷 / 04期

关键词：

modified starch; nickel complex; anionic dyes; adsorption; infrared spectra; ACTIVATED CARBON; ADSORPTION PROPERTIES; WASTE-WATER; ACID DYES; MECHANISM; AZO; DERIVATIVES; EARTH;

D O I：

10.1002/app.34836

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The work presents the synthesis of nickel (II) complex of dithiocarbamate-modified starch (DTCSNi). It is characterized by elemental analysis, infrared spectrum, and thermogravimetry methods. A batch system was applied to study the adsorption of DTCSNi for four anionic dyes removals. The adsorption with respect to the pH was investigated. It is found that the capacity of DTCSNi for each dye is pH dependent, and the adsorption is governed by coordination. At the suitable pH 4, two kinetic models, that is, pseudo-first-and pseudo-second-order, were tested to investigate the adsorption process. The kinetic parameters of the models were calculated and discussed. The results suggest that the best fit model is the pseudo-second-order equation. The Langmuir-Freundlich model agrees very well with experimental data and the maximum adsorption capacity sequence is AO7 > AG25 > AR18 > AO10. The Fourier transform infrared spectra and thermogravimetric analysis verified the chelating molecular mechanism. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 123: 2439-2444, 2012

引用

页码：2439 / 2444

页数：6

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