Novel Way to Harness Solar Energy: Photo-Redox Catalysis in Organic Synthesis

被引：6

作者：

Jain, A. ^{[1
]}

Ameta, C. ^{[2
]}

机构：

[1] St Xaviers Coll, Dept Chem, Mumbai 400001, Maharashtra, India

[2] ML Sukhadia Univ, Univ Coll Sci, Dept Chem, Photochem Lab, Udaipur 313002, Rajasthan, India

来源：

KINETICS AND CATALYSIS | 2020年 / 61卷 / 02期

关键词：

photo-redox catalysis; solar energy; C-H fuctionalization; coupling reactions; cycloaddition; reductive processes; oxidative processes; VISIBLE-LIGHT-PHOTOREDOX; C-H BOND; ALIPHATIC CARBOXYLIC-ACIDS; GRAPHITIC CARBON NITRIDE; ONE-POT SYNTHESIS; SELECTIVE OXIDATION; AEROBIC OXIDATION; DECARBOXYLATIVE FLUORINATION; PHOTOSENSITIZED OXIDATION; C(SP(3))-H ACTIVATION;

D O I：

10.1134/S002315842002007X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Visible light-mediated photo-redox catalysis has evolved as one of the exponentially growing fields in organic synthesis. The development of visible light-promoted photocatalytic reactions, which enable rapid and efficient synthesis of fine chemicals, is highly desirable from the viewpoint of cost, safety, availability, and environmental friendliness. The present review highlights the renaissance of interest in synthetic applications of photo-redox reactions. This powerful, enabling technology has led in the development of a remarkably diverse range of organic free radical and radical ion reactions, which have remarkable impact in the field of organic synthesis, materials science and pharmaceutical chemistry.

引用

页码：242 / 268

页数：27

共 221 条

[1] Improving the throughput of batch photochemical reactions using flow: Dual photoredox and nickel catalysis in flow for C(sp2)-C(sp3) cross-coupling [J].

Abdiaj, Irini ;

Alcazar, Jesus .

BIOORGANIC & MEDICINAL CHEMISTRY, 2017, 25 (23) :6190-6196

[2]

Aca T.A., 2018, ORG LETT, V20, P1546, DOI [10.1021/acs.orglett.8b00272, DOI 10.1021/ACS.ORGLETT.8B00272]

[3] Sunlight-driven trifluoromethylation of olefinic substrates by photoredox catalysis: A green organic process [J].

Akita, Munetaka ;

Koike, Takashi .

COMPTES RENDUS CHIMIE, 2015, 18 (07) :742-751

[4] Visible Light Photoredox Cross-Coupling of Acyl Chlorides with Potassium Alkoxymethyltrifluoroborates: Synthesis of α-Alkoxyketones [J].

Amani, Javad ;

Sodagar, Esmat ;

Molander, Gary A. .

ORGANIC LETTERS, 2016, 18 (04) :732-735

[5] Ethanol synthesis based on the photoredox system consisting of photosensitizer and dehydrogenases [J].

Amao, Yutaka ;

Shuto, Naho ;

Iwakuni, Hideharu .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2016, 180 :403-407

[6] Recent synthetic additions to the visible light photoredox catalysis toolbox [J].

Angnes, Ricardo A. ;

Li, Zhou ;

Correia, Carlos Roque D. ;

Hammond, Gerald B. .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2015, 13 (35) :9152-9167

[7] Trifluoromethylation of aromatic alkenes by visible-light-driven photoredox catalysis: Direct conversion of alkenes to 3-trifluoromethyl-1-propenyl and 1,3-bis(trifluoromethyl)-1-propenyl derivatives [J].

Asano, Masashi ;

Tomita, Ren ;

Koike, Takashi ;

Akita, Munetaka .

JOURNAL OF FLUORINE CHEMISTRY, 2015, 179 :83-88

[8] Photochemical Perfluoroalkylation with Pyridine N-Oxides: Mechanistic Insights and Performance on a Kilogram Scale [J].

Beatty, Joel W. ;

Douglas, James J. ;

Miller, Richard ;

McAtee, Rory C. ;

Cole, Kevin P. ;

Stephenson, Corey R. J. .

CHEM, 2016, 1 (03) :456-472

[9] Visible light photoredox and Polonovsld-Potier cyclizations for the synthesis of (±)-5-epi-cermizine C and (±)-epimyrtine [J].

Benimana, Shami Eden ;

Cromwell, Nicholle E. ;

Meer, Humna N. ;

Marvin, Christopher C. .

TETRAHEDRON LETTERS, 2016, 57 (46) :5062-5064

[10] Visible-Light-Mediated Oxygenation Reactions using Molecular Oxygen [J].

Bian, Changliang ;

Singh, Atul K. ;

Niu, Linbin ;

Yi, Hong ;

Lei, Aiwen .

ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2017, 6 (04) :386-396

← 1 2 3 4 5 6 7 8 9 10 →