Compositional dependence of the stability of AuCu alloy nanoparticles

被引：150
|
作者：
Xu, Zhichuan [1 ]
Lai, Erica [1 ]
Shao-Horn, Yang [1 ]
Hamad-Schifferli, Kimberly [1 ,2 ]
机构：
[1] MIT, Dept Mech Engn, Cambridge, MA 02139 USA
[2] MIT, Dept Biol Engn, Cambridge, MA 02139 USA
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 45期
关键词：
ELECTROCHEMICAL REDUCTION; COPPER NANOPARTICLES; OXIDATION; CO2; NANOCRYSTALS; ELECTRODES; MORPHOLOGY; METHANOL; OXYGEN; ROUTE;
D O I：
10.1039/c2cc31576a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The oxidation of AuCu nanoparticles was studied as a function of composition and temperature. Oxidation rates at 110 degrees C were higher for NPs with higher Cu content, showing that Au stabilized the Cu. Electrochemistry measurements show that AuCu could be a promising catalyst for lowering the over potential of CO2 reduction.
引用
收藏
页码：5626 / 5628
页数：3
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