The structure and magnetic properties of cobalt ferrite nanoparticles synthesized in a system of direct micelles of amphiphiles by means of ion flotoextraction
被引:3
作者:
Mirgorod, Yu. A.
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机构:
SW State Univ, Kursk 305040, RussiaSW State Univ, Kursk 305040, Russia
Mirgorod, Yu. A.
[1
]
Borshch, N. A.
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h-index: 0
机构:
SW State Univ, Kursk 305040, RussiaSW State Univ, Kursk 305040, Russia
Borshch, N. A.
[1
]
Fedosyuk, V. M.
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h-index: 0
机构:
Natl Acad Sci Belarus, Inst Solid State & Semicond Phys, SSPA Sci & Pract Ctr Mat Sci, Minsk 220072, BELARUSSW State Univ, Kursk 305040, Russia
Fedosyuk, V. M.
[2
]
Yurkov, G. Yu.
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机构:
Russian Acad Sci, Baikov Inst Met & Mat Sci, Moscow 119991, RussiaSW State Univ, Kursk 305040, Russia
ion flotoextraction;
direct micelles;
cobalt ferrite nanoparticles;
structure;
magnetic properties;
DEPENDENCE;
PHASE;
ZN;
D O I:
10.1134/S0036024412030211
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
A method for obtaining nanoparticles in a system of direct micelles of amphiphiles using ion flotoextraction for concentrating ions from diluted water solutions is developed. Nanoparticles of the composition CoFe2O4 with a structure close to spinel are obtained. It is established that the particles consist of two components: well-formed phases of cobalt ferrite CoFe2O4 and its amorphous analog. It is shown that the nanoparticles have a maximum size distribution ranging from 4 to 6 nm; on a carbon substrate, they self-organize into a periodic colloidal structure. It is concluded that nanosized CoFe2O4 powder has a blocking temperature of about 45 K, a magnetic moment of about 0.85-0.9 mu(B) at a temperature of 0 K, and the Neol temperature lies in the range of 110 to 250 K.