On the effective ionic radii for ammonium

被引:128
作者
Sidey, Vasyl [1 ,2 ]
机构
[1] Uzhgorod Natl Univ, Dept Chem, Pidgirna St 46, UA-88000 Uzhgorod, Ukraine
[2] Uzhgorod Natl Univ, Res Inst Phys & Chem Solids, Pidgirna St 46, UA-88000 Uzhgorod, Ukraine
关键词
ammonium; ionic radii; bond valence model; BOND-VALENCE PARAMETERS; LENGTH CORRELATION CURVE; X-RAY-DIFFRACTION; CRYSTAL-STRUCTURE; NEUTRON-DIFFRACTION; THERMAL-EXPANSION; EMPIRICAL-MODEL; VARIANT;
D O I
10.1107/S2052520616008064
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A set of effective ionic radii corresponding to different coordination numbers (CNs) and compatible with the radii system by Shannon [Acta Cryst. (1976), A32, 751-767] has been derived for ammonium: 1.40 angstrom (CN = IV), 1.48 angstrom (CN = VI), 1.54 angstrom (CN = VIII) and 1.67 angstrom (CN = XII). The bond-valence parameters r(0) = 2.3433 angstrom and B = 0.262 angstrom have been determined for ammonium-fluorine bonds.
引用
收藏
页码:626 / 633
页数:8
相关论文
共 63 条
[1]   RAPIDLY RUNNING TRANSITIONS AT HIGH PRESSURE [J].
ADAMS, LH ;
DAVIS, BL .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1962, 48 (06) :982-&
[2]   THE USE OF IONIZATION POTENTIALS .1. IONIC RADII OF THE ELEMENTS [J].
AHRENS, LH .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1952, 2 (03) :155-169
[3]   RELATIONS BETWEEN BOND LENGTHS AND BOND STRENGTHS IN OXIDE STRUCTURES [J].
ALLMANN, R .
MONATSHEFTE FUR CHEMIE, 1975, 106 (03) :779-793
[4]  
[Anonymous], ANN ACAD SCI FENN A
[5]  
[Anonymous], 1960, The Nature of the Chemical Bond, 3rd ed
[6]  
[Anonymous], IUCR MONOGRAPH CRYST
[7]  
Baur W.H., 1970, Trans Am Crystallogr Assoc, V6, P125
[8]   SIMILARITY OF ATOMIC RADIOS OF PALLADIUM (2) AND PALLADIUM (4) [J].
BELL, JD ;
HALL, D ;
WATERS, TN .
ACTA CRYSTALLOGRAPHICA, 1966, 21 :440-&
[9]   INTERMOLECULAR EFFECTS ON THE GEOMETRY OF [PTCL4]2- - X-RAY-DIFFRACTION STUDIES OF AQUEOUS H2PTCL4 AND CRYSTALLINE (NH4)2PTCL4 [J].
BENGTSSON, LA ;
OSKARSSON, A .
ACTA CHEMICA SCANDINAVICA, 1992, 46 (08) :707-711
[10]   BOND-VALENCE PARAMETERS FOR SOLIDS [J].
BRESE, NE ;
OKEEFFE, M .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 :192-197