Using Singlet Oxygen to Synthesize Natural Products and Drugs

被引：587

作者：

Ghogare, Ashwini A. ^{[1
,2
]}

Greer, Alexander ^{[1
,2
]}

机构：

[1] CUNY Brooklyn Coll, Dept Chem, 2900 Bedford Ave, Brooklyn, NY 11210 USA

[2] CUNY, Grad Ctr, PhD Program Chem, 365 Fifth Ave, New York, NY 10016 USA

来源：

CHEMICAL REVIEWS | 2016年 / 116卷 / 17期

基金：

美国国家科学基金会;

关键词：

DYE-SENSITIZED PHOTOOXYGENATION; BIOMIMETIC TOTAL-SYNTHESIS; 1ST TOTAL-SYNTHESIS; BIOACTIVE CYCLIC PEROXIDES; LOW-TEMPERATURE OZONATION; GAS-PHASE KINETICS; ONE-POT SYNTHESIS; ENE-REACTION; PHOTOSENSITIZED OXIDATION; STEREOSPECIFIC SYNTHESIS;

D O I：

10.1021/acs.chemrev.5b00726

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This Review describes singlet oxygen (O-2) in the organic synthesis of targets on possible O-1(2), biosynthetic routes. The visible-light sensitized production of O-1(2) is not only useful for synthesis; it is extremely common in nature. This Review is intended to draw a logical link between flow and batch reactions a combination that leads to the current state of O-1(2) in synthesis.

引用

页码：9994 / 10034

页数：41

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