From Pasteur to chiral ionic liquids: a short history of solvent-promoted asymmetric induction

被引：0
|
作者：
Gaumont, Annie-Claude [2 ]
Genisson, Yves [1 ]
Guillen, Frederic [3 ]
Plaquevent, Jean-Christophe [1 ]
机构：
[1] Univ Toulouse 3, CNRS, UMR 5068, Lab Synth & Physicochim Mol Interat Biol, F-31062 Toulouse 9, France
[2] ENSICAEN, INC3M FR 3038, CNRS, Lab Chim Mol & Thioorgan,UMR 6507, F-14050 Caen, France
[3] Univ Rouen, COBRA, CNRS, IRCOF,UMR 6014, F-76821 Mont St Aignan, France
来源：
ACTUALITE CHIMIQUE | 2011年 / 348-49期
关键词：
Chirality; ionic liquids; chiral solvents; asymmetric synthesis; BAYLIS-HILLMAN REACTION; ACID; CHEMISTRY; DESIGN; MEDIA;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
From Pasteur to chiral ionic liquids: a short history of solvent-promoted asymmetric induction Among numerous approaches for the asymmetric construction of chiral molecules, the use of chiral solvents was occulted for a long period. However, thanks to the recent apparition of ionic liquids, green solvents with unprecedented structural modularity, this particular approach in asymmetric synthesis is renewed.
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页码：84 / 89
页数：6
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