Up-conversion white light of Tm3+/Er3+/Yb3+ tri-doped CaF2 phosphors

被引:85
作者
Cao, Chunyan [2 ,3 ]
Qin, Weiping [1 ,2 ]
Zhang, Jisen [2 ]
Wang, Yan [2 ,3 ]
Wang, Guofeng [1 ]
Wei, Guodong [1 ]
Zhu, Peifen [1 ]
Wang, Lili [1 ]
Jin, Longzhen [1 ]
机构
[1] Jilin Univ, Coll Elect Sci & Engn, State Key Lab Integrated Optoelectron, Changchun 130012, Peoples R China
[2] Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, Key Lab Excited State Processes, Changchun 130033, Peoples R China
[3] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
up-conversion; white light; Tm3+/Er3+/Yb3+ tri-doped CaF2;
D O I
10.1016/j.optcom.2007.11.045
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Tm3+/Er3+/Yb3+ tri-doped CaF2 phosphors were synthesized using a hydrothermal method. The phosphors were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and up-conversion (UC) emission spectra. After annealing, the phosphors emitted white light under a 980 nm continuous wave diode laser (CW LD 2 W) excitation. As the excitation power density changed in the range of 20-260 W/cm(2), the chromaticity coordinates of the UC light of the phosphor Ca0.885Tm0.005Er0.01Yb0.1F2 well in the white region of the 1931 CIE diagram. For the proportion of red, green and blue (RGB) in white light is strict, key factors for achieving UC white light, such as host materials, rare earth ions doping concentrations, annealing temperatures, as well as the excitation power densities, were investigated and discussed. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:1716 / 1719
页数:4
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