A novel and reusable magnetic nanocatalyst developed based on graphene oxide incorporated strontium nanoparticles for the facial synthesis of β-enamino ketones under solvent-free conditions

被引:19
作者
Mousavi, Seyyed Rasul [1 ]
Sereshti, Hassan [2 ]
Nodeh, Hamid Rashidi [2 ,3 ]
Foroumadi, Alireza [1 ,4 ]
机构
[1] Univ Tehran Med Sci, TIPS, Drug Design & Dev Res Ctr, Tehran, Iran
[2] Univ Tehran, Dept Chem, Fac Sci, Tehran, Iran
[3] SRI, Fac Food Ind & Agr, Dept Food Sci & Technol, POB 31745-139, Karaj, Iran
[4] Kerman Univ Med Sci, Inst Neuropharmacol, Neurosci Res Ctr, Kerman, Iran
关键词
graphene oxide; magnetic nanocatalyst; solvent-free; strontium; beta-enamino ketone; EFFICIENT SYNTHESIS; CARBON NANOTUBES; SULFURIC-ACID; ESTERS; CATALYST; REDUCTION; REMOVAL; 3-AMINOPROPENOATES; DEGRADATION; DERIVATIVES;
D O I
10.1002/aoc.4644
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A novel magnetic SrFeGO nanocatalyst (NC) was synthesized through a simple sol-gel technique by introducing strontium and iron oxide nanoparticles onto graphene. The synthesized NC was characterized using FT-IR and FE-SEM. Subsequently, the catalytic activity of SrFeGO was tested in a reaction between beta-dicarbonyl compounds and aniline derivatives to gain beta-enamino ketone derivatives under solvent-free conditions. It was found that SrFeGO NC is a potential catalyst for the synthesis of beta-enamino ketones. The beta-enamino ketone produced by such reactions could be isolated in high purity without the need for chromatographic purifications. The newly prepared magnetic graphene oxide nanocomposite could be recovered and reused for numerous times with no significant decrease in efficiency. Moreover, the protocol has the advantages of excellent yielding (up to 98%) in short a reaction time, benefitting an easy workup procedure and being environmentally friendly.
引用
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页数:9
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