Efficient Sonogashira and Suzuki-Miyaura coupling reaction catalyzed by Pd-Nanoparticles

被引:9
作者
Balsane, Kishor E. [1 ]
Shendage, Suresh S. [1 ]
Nagarkar, Jayashree M. [1 ]
机构
[1] Inst Chem Technol, Dept Chem, Bombay 400019, Maharashtra, India
关键词
Electrochemistry; Palladium nanoparticles; Nafion-graphene; heterogeneous recyclable catalyst; ARENEDIAZONIUM TETRAFLUOROBORATE SALTS; PALLADIUM NANOPARTICLES; ELECTROCHEMICAL SYNTHESIS; ARYLBORONIC ACIDS; BORONIC ACIDS; ARYL; SUPPORT; LIGAND;
D O I
10.1007/s12039-015-0796-z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Pd nano particles were electrochemically deposited on nafion-graphene. They showed excellent catalytic activity towards Sonogashira and Suzuki-Miyaura cross-coupling reaction. Benzenediazonium salts were used as alternative to aromatic halide. The developed protocol offers recyclability, easy workups with short reaction time and good-to-excellent product yield.
引用
收藏
页码:425 / 431
页数:7
相关论文
共 36 条
[21]   Pd-grafted periodic mesoporous organosilica: an efficient heterogeneous catalyst for Hiyama and Sonogashira couplings, and cyanation reactions [J].
Modak, Arindam ;
Mondal, John ;
Bhaumik, Asim .
GREEN CHEMISTRY, 2012, 14 (10) :2840-2855
[22]   Palladium-catalyzed alkynylation [J].
Negishi, E ;
Anastasia, L .
CHEMICAL REVIEWS, 2003, 103 (05) :1979-2017
[23]  
Paterson I, 2001, ANGEW CHEM INT EDIT, V40, P603, DOI 10.1002/1521-3773(20010202)40:3<603::AID-ANIE603>3.0.CO
[24]  
2-O
[25]   Suzuki-Miyaura cross-coupling of arenediazonium salts with arylboronic acids catalyzed by a recyclable polymer-supported N-heterocyclic carbene-palladium catalyst [J].
Qin, Yuancheng ;
Wei, Wei ;
Luo, Meiming .
SYNLETT, 2007, (15) :2410-2414
[26]   Functionalized graphene sheets for polymer nanocomposites [J].
Ramanathan, T. ;
Abdala, A. A. ;
Stankovich, S. ;
Dikin, D. A. ;
Herrera-Alonso, M. ;
Piner, R. D. ;
Adamson, D. H. ;
Schniepp, H. C. ;
Chen, X. ;
Ruoff, R. S. ;
Nguyen, S. T. ;
Aksay, I. A. ;
Prud'homme, R. K. ;
Brinson, L. C. .
NATURE NANOTECHNOLOGY, 2008, 3 (06) :327-331
[27]   COORDINATION, ATOM REORGANIZATION, AND CATALYSIS OF PALLADIUM IN ZEOLITE CAGES [J].
SACHTLER, WMH ;
CAVALCANTI, FAP ;
ZHANG, Z .
CATALYSIS LETTERS, 1991, 9 (3-4) :261-272
[28]   Electrocatalytically Active Graphene-Platinum Nanocomposites. Role of 2-D Carbon Support in PEM Fuel Cells [J].
Seger, Brian ;
Kamat, Prashant V. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (19) :7990-7995
[29]   PdCo bimetallic nanoparticles supported on PPI-grafted graphene as an efficient catalyst for Sonogashira reactions [J].
Shaabani, Ahmad ;
Mahyari, Mojtaba .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (32) :9303-9311
[30]   Electrochemical synthesis and characterization of palladium nanoparticles on nafion-graphene support and its application for Suzuki coupling reaction [J].
Shendage, Suresh S. ;
Patil, Umakant B. ;
Nagarkar, Jayashree M. .
TETRAHEDRON LETTERS, 2013, 54 (26) :3457-3461