Solvent effects on hydrogen bonding between ethyl methacrylate and 1-butanol

被引：30

作者：

Sivagurunathan, P ^{[1
]}

Dharmalingam, K ^{[1
]}

Ramachandran, K ^{[1
]}

机构：

[1] Annamalai Univ, Dept Phys, Annamalainagar 608002, Tamil Nadu, India

来源：

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | 2005年 / 219卷 / 10期

关键词：

FTIR spectroscopy; hydrogen bonding; 1 : 1 complex; solvent effect;

D O I：

10.1524/zpch.2005.219.10_2005.1385

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The hydrogen bonding between ethyl methacrylate dissolved in 1-butanol in inert solvents viz., n-heptane, carbon tetrachloride and benzene has been studied using FTIR spectroscopy. Utilizing Nash method the formation constant of the I : I complexes has been calculated. The formation constant and free energy change values vary with the solvents are observed in the present study confirms the solvent environment may affect the strength of intermolecular hydrogen bond formation between free hydroxyl group of 1-butanol and the carbonyl group of ethyl methacrylate.

引用

页码：1385 / 1390

页数：6

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